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author | prashantsinalkar | 2020-04-14 10:19:27 +0530 |
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committer | prashantsinalkar | 2020-04-14 10:23:54 +0530 |
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tree | 2b1df110e24ff0174830d7f825f43ff1c134d1af /Modern_Physics_by_R_A_Serway/11-Molecular_Structure.ipynb | |
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diff --git a/Modern_Physics_by_R_A_Serway/11-Molecular_Structure.ipynb b/Modern_Physics_by_R_A_Serway/11-Molecular_Structure.ipynb new file mode 100644 index 0000000..e674f8e --- /dev/null +++ b/Modern_Physics_by_R_A_Serway/11-Molecular_Structure.ipynb @@ -0,0 +1,106 @@ +{ +"cells": [ + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "# Chapter 11: Molecular Structure" + ] + }, +{ + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 11.1: Rotation_of_CO_molecule.sce" + ] + }, + { +"cell_type": "code", + "execution_count": null, + "metadata": { + "collapsed": true + }, + "outputs": [], +"source": [ +"// Scilab code Ex11.1: Pg 380 (2005)\n", +"clc; clear;\n", +"// Part (a)\n", +"f = 1.15e+11; // Frequency of transitions, Hz\n", +"omega = 2*(%pi)*f; // Angular frequency of absorbed radiations, Hz\n", +"h_cross = 1.055e-34; // Reduced planks constant, J-s\n", +"// Since E = (h_cross)^2/I_CM = h_cross*omega, solving for I_CM\n", +"I_CM = h_cross/omega; // Moment of inertia of molecule about its center of mass, kg-m^2\n", +"printf('\nThe moment of inertia of molecule about its center of mass = %4.2e kg-m^2', I_CM);\n", +"\n", +"// Part (b)\n", +"m_O = 16; // Mass of oxygen atom, a.m.u\n", +"m_C = 12; // Mass of carbon atom, a.m.u\n", +"mu = ( m_O * m_C *0.166e-26)/(m_O + m_C); // Reduced mass, kg\n", +"// Since I_CM = mew*R_o^2, solving for R_o\n", +"R_0 = sqrt(I_CM/mu); // Bond length of carbon monoxide molecule, m \n", +"printf('\nThe bond length of carbon monoxide molecule = %5.3f nm', R_0/1e-09);\n", +"\n", +"// Result\n", +"// The moment of inertia of molecule about its center of mass = 1.46e-046 kg-m^2\n", +"// The bond length of carbon monoxide molecule = 0.113 nm " + ] + } +, +{ + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 11.2: Variation_of_CO_molecule.sce" + ] + }, + { +"cell_type": "code", + "execution_count": null, + "metadata": { + "collapsed": true + }, + "outputs": [], +"source": [ +"// Scilab code Ex11.2: Pg 383 (2005)\n", +"clc; clear;\n", +"\n", +"// Part (a)\n", +"f = 6.42e+13; // Frequency of absorption, Hz\n", +"omega = 2*(%pi)*f; // Angular frequency of absorbed radiations, Hz\n", +"mu = 1.14e-26; // Reduced mass of CO molecule, kg\n", +"K = mu*(omega^2); // Effective force constant of CO molecule, N/m\n", +"printf('\nThe effective force constant of CO molecule = %4.2e N/m', K);\n", +"\n", +"// Part (b)\n", +"h_cross = 1.055e-34; // Reduced Planck's constant, J-s\n", +"A = sqrt(h_cross/(mu*omega)); // Amplitude of vibrations, m\n", +"printf('\nThe amplitude of vibrations = %7.5f nm', A/1e-09);\n", +"\n", +"// Result\n", +"// The effective force constant of CO molecule = 1.85e+003 N/m\n", +"// The amplitude of vibrations = 0.00479 nm " + ] + } +], +"metadata": { + "kernelspec": { + "display_name": "Scilab", + "language": "scilab", + "name": "scilab" + }, + "language_info": { + "file_extension": ".sce", + "help_links": [ + { + "text": "MetaKernel Magics", + "url": "https://github.com/calysto/metakernel/blob/master/metakernel/magics/README.md" + } + ], + "mimetype": "text/x-octave", + "name": "scilab", + "version": "0.7.1" + } + }, + "nbformat": 4, + "nbformat_minor": 0 +} |