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// Given:-
// Applying the conservation of mass principle, the overall dissociation reaction is described by
// CO2 --- zCO2 + (1-z)CO + ((1-z)/2)O2
p = 1.0 // in atm
pref = 1.0 // in atm
// At 3200 K, Table A-27 gives
log10k = -.189
// Solving k = ((1-z)/2)*((1-z)/(3-z))^.5 gives
z = 0.422
// Calculations
k = 10**log10k
// From tables A-25 and A-23
hfbarCO2 = -393520.0 // in kj/kmol
deltahbarCO2 = 174695-9364 // in kj/kmol
hfbarCO = -110530.0 // in kj/kmol
deltahbarCO = 109667-8669 // in kj/kmol
hfbarO2 = 0 // in kj/kmol
deltahbarO2 = 114809-8682 // in kj/kmol
hfbarCO2r = -393520.0 // in kj/kmol
deltahbarCO2r = 0 // in kj/kmol
Qcvdot = 0.422*(hfbarCO2 + deltahbarCO2) + 0.578*(hfbarCO + deltahbarCO) + 0.289*(hfbarO2 + deltahbarO2)- (hfbarCO2r + deltahbarCO2r)
// Result
printf( ' The heat transfer to the reactor, in kJ per kmol of CO2 entering is: %f', Qcvdot);
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