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Diffstat (limited to '3012/CH14/EX14.5/Ex14_5.sce')
-rwxr-xr-x | 3012/CH14/EX14.5/Ex14_5.sce | 28 |
1 files changed, 28 insertions, 0 deletions
diff --git a/3012/CH14/EX14.5/Ex14_5.sce b/3012/CH14/EX14.5/Ex14_5.sce new file mode 100755 index 000000000..0d2047373 --- /dev/null +++ b/3012/CH14/EX14.5/Ex14_5.sce @@ -0,0 +1,28 @@ + +// Given:- +// Applying the conservation of mass principle, the overall dissociation reaction is described by +// CO2 --- zCO2 + (1-z)CO + ((1-z)/2)O2 + +p = 1.0 // in atm +pref = 1.0 // in atm +// At 3200 K, Table A-27 gives +log10k = -.189 +// Solving k = ((1-z)/2)*((1-z)/(3-z))^.5 gives +z = 0.422 + +// Calculations +k = 10**log10k +// From tables A-25 and A-23 +hfbarCO2 = -393520.0 // in kj/kmol +deltahbarCO2 = 174695-9364 // in kj/kmol +hfbarCO = -110530.0 // in kj/kmol +deltahbarCO = 109667-8669 // in kj/kmol +hfbarO2 = 0 // in kj/kmol +deltahbarO2 = 114809-8682 // in kj/kmol +hfbarCO2r = -393520.0 // in kj/kmol +deltahbarCO2r = 0 // in kj/kmol + +Qcvdot = 0.422*(hfbarCO2 + deltahbarCO2) + 0.578*(hfbarCO + deltahbarCO) + 0.289*(hfbarO2 + deltahbarO2)- (hfbarCO2r + deltahbarCO2r) + +// Result +printf( ' The heat transfer to the reactor, in kJ per kmol of CO2 entering is: %f', Qcvdot); |