diff options
Diffstat (limited to '3856/CH10/EX10.1/Ex10_1.sce')
-rw-r--r-- | 3856/CH10/EX10.1/Ex10_1.sce | 30 |
1 files changed, 30 insertions, 0 deletions
diff --git a/3856/CH10/EX10.1/Ex10_1.sce b/3856/CH10/EX10.1/Ex10_1.sce new file mode 100644 index 000000000..02d659e31 --- /dev/null +++ b/3856/CH10/EX10.1/Ex10_1.sce @@ -0,0 +1,30 @@ +//Calculate the Equilibrium constant for the reaction Sn(s)+2Ag(one positive)(aq)=Sn(double positive)(aq)+2Ag(s). And also predict whether the given reaction would occur spontaneously under standard-state condition
+
+//Example 10.1
+
+clc;
+
+clear;
+
+Ecathode=0.800; //Standard Electrode Potential for Ag in V
+
+Eanode=-0.138; //Standard Electrode Potential for Sn in V
+
+E=Ecathode-Eanode; //Standard Electrode Potential for Electrochemical cell (positive quantity of E shows the reaction is spontaneous under standard-state condition)
+
+F=96500; //Faraday costant in C mol^-1
+
+v=2; //Stoichiometric coefficient (two electron are transferred in reaction)
+
+R=8.314; //Gas constant in J K^-1 mol^-1
+
+T=25+273; //Temperature in K
+
+K=exp((v*E*F)/(R*T)); //Equilibrium constant
+
+printf("Equilibrium constant = %.1f*10^31",K*10^-31);
+
+delrG=(-v*F*E)/1000; //Gibbs Energy in kJ mol^-1 (large negative value of delrG indicate that the reaction is spontaneous under standard state condition)
+
+printf("\n Spontaneity of the reactin = %.0f kJ mol^-1",delrG);
+
|