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| author | priyanka | 2015-06-24 15:03:17 +0530 |
|---|---|---|
| committer | priyanka | 2015-06-24 15:03:17 +0530 |
| commit | b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (patch) | |
| tree | ab291cffc65280e58ac82470ba63fbcca7805165 /572/CH13/EX13.10 | |
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Diffstat (limited to '572/CH13/EX13.10')
| -rwxr-xr-x | 572/CH13/EX13.10/c13_10.sce | 26 |
1 files changed, 26 insertions, 0 deletions
diff --git a/572/CH13/EX13.10/c13_10.sce b/572/CH13/EX13.10/c13_10.sce new file mode 100755 index 000000000..fc3c8493d --- /dev/null +++ b/572/CH13/EX13.10/c13_10.sce @@ -0,0 +1,26 @@ +//(13.10) Determine the change in entropy of the system of Example 13.6 in kJ/K.
+
+
+//solution
+Rbar = 8.314 //universal gas constant in SI units
+//The chemical equation for the complete combustion of methane with oxygen is
+//CH4 + 2O2 ----> CO2 + 2H2O
+yCH4 = 1/3
+yO2 = 2/3
+yCO2 = 1/3
+yH2O = 2/3
+//from table A-25
+sbarCH4atTref = 186.16 //in kj/kmol.K
+sbarO2atTref = 205.03 //in kj/kmol.K
+
+sbarCH4 = sbarCH4atTref - Rbar*log(yCH4)
+sbarO2 = sbarO2atTref - Rbar*log(yO2)
+
+p2 = 3.02 //in atm
+pref = 1 //in atm
+//with help from table A-23
+sbarCO2 = 263.559 - Rbar*log(yCO2*p2/pref) //in kj/kmol.K
+sbarH2O = 228.321 - Rbar*log(yH2O*p2/pref) //in kj/kmol.K
+
+deltaS = sbarCO2 + 2*sbarH2O - sbarCH4 -2*sbarO2 //in kj/K
+printf('the chenge in entropy of the system in kJ/K is: %f',deltaS)
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