From b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b Mon Sep 17 00:00:00 2001 From: priyanka Date: Wed, 24 Jun 2015 15:03:17 +0530 Subject: initial commit / add all books --- 572/CH13/EX13.10/c13_10.sce | 26 ++++++++++++++++++++++++++ 1 file changed, 26 insertions(+) create mode 100755 572/CH13/EX13.10/c13_10.sce (limited to '572/CH13/EX13.10') diff --git a/572/CH13/EX13.10/c13_10.sce b/572/CH13/EX13.10/c13_10.sce new file mode 100755 index 000000000..fc3c8493d --- /dev/null +++ b/572/CH13/EX13.10/c13_10.sce @@ -0,0 +1,26 @@ +//(13.10) Determine the change in entropy of the system of Example 13.6 in kJ/K. + + +//solution +Rbar = 8.314 //universal gas constant in SI units +//The chemical equation for the complete combustion of methane with oxygen is +//CH4 + 2O2 ----> CO2 + 2H2O +yCH4 = 1/3 +yO2 = 2/3 +yCO2 = 1/3 +yH2O = 2/3 +//from table A-25 +sbarCH4atTref = 186.16 //in kj/kmol.K +sbarO2atTref = 205.03 //in kj/kmol.K + +sbarCH4 = sbarCH4atTref - Rbar*log(yCH4) +sbarO2 = sbarO2atTref - Rbar*log(yO2) + +p2 = 3.02 //in atm +pref = 1 //in atm +//with help from table A-23 +sbarCO2 = 263.559 - Rbar*log(yCO2*p2/pref) //in kj/kmol.K +sbarH2O = 228.321 - Rbar*log(yH2O*p2/pref) //in kj/kmol.K + +deltaS = sbarCO2 + 2*sbarH2O - sbarCH4 -2*sbarO2 //in kj/K +printf('the chenge in entropy of the system in kJ/K is: %f',deltaS) \ No newline at end of file -- cgit