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authorprashantsinalkar2017-10-10 12:27:19 +0530
committerprashantsinalkar2017-10-10 12:27:19 +0530
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+//Calculate the value of change in Internal energy and change in Enthalpy for the combution of Benzoic acid
+
+//Example 4.3
+
+clc;
+
+clear;
+
+C=5267.8; //Effective heat capcity of bomb calorimeter plus water im J K^-1
+
+T1=293.32; //Initial temperature in K
+
+T2=295.37; //Final temperature in K
+
+delT=T2-T1; //Change in teperature in K
+
+M=122.12; //Molar mass of Benzoic acid in g mol^-1
+
+m=0.4089; //Mass of sample of Benzoic acid in g
+
+delU=-(C*delT*M)/(m*1000); //Change in Enternal enegy in kJ mol^-1
+
+printf("Change in Enternal energy = %.0f kJ mol^-1",delU);(The answer vary due to round off error)
+
+R=8.314; //Gas constant in J K^-1 mol^-1
+
+T=T1; //Temperature in K
+
+n1=7.5; //Number of moles of gas for reactants
+
+n2=7; //Number of mole of gas for product
+
+deln=n2-n1; //Change of moles gas for reaction
+
+delH=delU+((R*T*deln)/1000); //Change in Enthalpy in kJ mol^-1
+
+printf("\nChange in Enthalpy = %.0f kJ mol^-1",delH);
diff --git a/3856/CH4/EX4.3/Ex4_3.txt b/3856/CH4/EX4.3/Ex4_3.txt
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+ Change in Enternal energy = -3225 kJ mol^-1
+Change in Enthalpy = -3226 kJ mol^-1 \ No newline at end of file