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author | priyanka | 2015-06-24 15:03:17 +0530 |
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committer | priyanka | 2015-06-24 15:03:17 +0530 |
commit | b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (patch) | |
tree | ab291cffc65280e58ac82470ba63fbcca7805165 /2912/CH7/EX7.9 | |
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-rwxr-xr-x | 2912/CH7/EX7.9/Ex7_9.sce | 24 |
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diff --git a/2912/CH7/EX7.9/Ex7_9.sce b/2912/CH7/EX7.9/Ex7_9.sce new file mode 100755 index 000000000..611ecfb4a --- /dev/null +++ b/2912/CH7/EX7.9/Ex7_9.sce @@ -0,0 +1,24 @@ +// chapter 7
+// example 7.9
+// calculate polarisability due to permanent dipole moment and due to deformation of the molecules
+// page 190-191
+clear;
+clc;
+// given
+alpha1=2.5E-39; // in C^2-m/N (dielectric constant at 300K)
+alpha2=2.0E-39; // in C^2-m/N (dielectric constant at 400K)
+T1=300; // in K(first temperature)
+T2=400; // in K(second temperature)
+//calculate
+// since alpha=alpha_d+alpha0 and alpha0=Beta/T
+// therefore alpha=alpha_d+(Beta/T)
+// since alpha1=alpha_d+(Beta/T1) and alpha2=alpha_d+(Beta/T2)
+// therefore alpha1-apha2=Beta*((1/T1)-(1/T2))
+// or Beta= (alpha1-apha2)/ ((1/T1)-(1/T2))
+Beta= (alpha1-alpha2)/ ((1/T1)-(1/T2)); // calculation of Beta
+alpha_d=alpha1-(Beta/T1); // calculation of polarisability due to defromation
+alpha0_1=Beta/T1; // calculation of polarisability due to permanent dipole moment at 300K
+alpha0_2=Beta/T2; // calculation of polarisability due to permanent dipole moment at 400K
+printf('\nThe polarisability due to permanent dipole moment at 300K is \t %1.2E C^2-m/N',alpha0_1);
+printf('\nThe polarisability due to permanent dipole moment at 400K is \t %1.2E C^2-m/N',alpha0_2);
+printf('\n\nThe polarisability due to deformation of the molecules is \t %1.2E C^2-m/N',alpha_d);
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