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authorpriyanka2015-06-24 15:03:17 +0530
committerpriyanka2015-06-24 15:03:17 +0530
commitb1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (patch)
treeab291cffc65280e58ac82470ba63fbcca7805165 /1967/CH18
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Diffstat (limited to '1967/CH18')
-rwxr-xr-x1967/CH18/EX18.1/18_1.sce11
-rwxr-xr-x1967/CH18/EX18.2/18_2.sce12
-rwxr-xr-x1967/CH18/EX18.3/18_3.sce12
-rwxr-xr-x1967/CH18/EX18.4/18_4.sce16
-rwxr-xr-x1967/CH18/EX18.5/18_5.sce13
-rwxr-xr-x1967/CH18/EX18.6/18_6.sce12
-rwxr-xr-x1967/CH18/EX18.7/18_7.sce27
7 files changed, 103 insertions, 0 deletions
diff --git a/1967/CH18/EX18.1/18_1.sce b/1967/CH18/EX18.1/18_1.sce
new file mode 100755
index 000000000..2aa604b41
--- /dev/null
+++ b/1967/CH18/EX18.1/18_1.sce
@@ -0,0 +1,11 @@
+clc
+//initialisation of variables
+clear
+k1= 16.4 //ml mole^-1
+k2= 2.5 //ml mole^-2
+k3= -1.2 //ml mole^-3
+m= 1 //molal
+//CALCULATIONS
+Ov= k1+k2*m+k3*m^2
+//RESULTS
+printf ('Apparent molar volume = %.1f ml mole^-1',Ov)
diff --git a/1967/CH18/EX18.2/18_2.sce b/1967/CH18/EX18.2/18_2.sce
new file mode 100755
index 000000000..11b5f9a07
--- /dev/null
+++ b/1967/CH18/EX18.2/18_2.sce
@@ -0,0 +1,12 @@
+clc
+//initialisation of variables
+clear
+n= 1 //mole
+n1= 400 //mole
+T= 25 //C
+H1= 5410 //cal
+H2= -5020 //cal
+//CALCULATIONS
+dH= -(H1+H2)
+//RESULTS
+printf ('Heat required to remove the water = %.f cal',dH)
diff --git a/1967/CH18/EX18.3/18_3.sce b/1967/CH18/EX18.3/18_3.sce
new file mode 100755
index 000000000..71ea40d1d
--- /dev/null
+++ b/1967/CH18/EX18.3/18_3.sce
@@ -0,0 +1,12 @@
+clc
+//initialisation of variables
+clear
+n= 1 //mole
+n1= 400 //mole
+T= 25 //C
+H1= 23540 //cal
+H2= -5410 //cal
+//CALCULATIONS
+dH= -(H1+H2)
+//RESULTS
+printf ('Heat required to remove the water = %.f cal',dH)
diff --git a/1967/CH18/EX18.4/18_4.sce b/1967/CH18/EX18.4/18_4.sce
new file mode 100755
index 000000000..8c42c802d
--- /dev/null
+++ b/1967/CH18/EX18.4/18_4.sce
@@ -0,0 +1,16 @@
+clc
+//initialisation of variables
+clear
+n1= 1 //mole
+n2= 400 //mole
+H1= 5638 //cal
+H2= 23540 //cal
+L= -1.54 //cal/mole
+l1= -2.16 //cal/mole
+l2= 5842 //cal/mole
+//CALCULATIONS
+Q1= n2*L+H1+H2
+Q2= n2*l1+2*l2
+Q= Q2-Q1
+//RESULTS
+printf ('Heat change = %.f cal',Q)
diff --git a/1967/CH18/EX18.5/18_5.sce b/1967/CH18/EX18.5/18_5.sce
new file mode 100755
index 000000000..59c2d840f
--- /dev/null
+++ b/1967/CH18/EX18.5/18_5.sce
@@ -0,0 +1,13 @@
+clc
+//initialisation of variables
+clear
+L2= 6000 //cal
+v= 3
+T= 25 //C
+T1= 0 //C
+//CALCULATIONS
+R= ((L2/(v*4.576))*(T-T1)/((273+T1)*(273+T)))
+r= 10^((L2/(v*4.576))*(T-T1)/((273+T1)*(273+T)))
+//RESULTS
+printf ('Ratio = %.3f ',R)
+printf ('\n Relative change in mean ionic coefficient = %.2f ',r)
diff --git a/1967/CH18/EX18.6/18_6.sce b/1967/CH18/EX18.6/18_6.sce
new file mode 100755
index 000000000..48221d258
--- /dev/null
+++ b/1967/CH18/EX18.6/18_6.sce
@@ -0,0 +1,12 @@
+clc
+//initialisation of variables
+clear
+L2= 4120 //cal
+l= -108 //cal mole^-1
+L21= -306 //cal mole^-1
+n1= 55.5 //moles
+n2= 1 //mole
+//CALCULATIONS
+Q= L21+L2
+//RESULTS
+printf ('differential heat of solution = %.f cal mole^-1',Q)
diff --git a/1967/CH18/EX18.7/18_7.sce b/1967/CH18/EX18.7/18_7.sce
new file mode 100755
index 000000000..9499a9f8c
--- /dev/null
+++ b/1967/CH18/EX18.7/18_7.sce
@@ -0,0 +1,27 @@
+clc
+//initialisation of variables
+clear
+n1= 2 //moles
+n2= 100 //moles
+Cp1= 17.9 //cal deg^-1 mole^-1
+Cp2= 21.78 //cal deg^-1 mole^-1
+T1= 30 //C
+T2= 25 //C
+L1= 5780 //cal
+L2= 5410 //cal
+h= 5620 //cal mole^-1
+n3= 3 //moles
+Cp3= 16.55 //cal deg^-1 mole^-1
+//CALCULATIONS
+Cp= n2*Cp1+n1*Cp2
+Q= (T2-T1)*Cp
+Q1= (n1*L1+L2)
+Q2= n3*h
+dQ= Q2-Q1
+dH= Q+dQ
+HC= 300*Cp1+n3*Cp3
+t= -dH/HC
+Tf= T2+t
+//RESULTS
+printf ('Increase in temperature = %.2f deg',t)
+printf ('\n Final temperature = %.1f deg',Tf)