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+{
+ "metadata": {
+ "name": "CH17"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter 17: Corrosion and Degradiation of Materials"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 3,
+ "metadata": {},
+ "source": [
+ "Example 17.1 Page No 629"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Determination of Electrochemical Cell Characteristics\n",
+ "\n",
+ "#Given\n",
+ "V_Cd=-0.403 #Half Cell Potential of Cd++|Cd\n",
+ "V_Ni=-0.250 #Half Cell Potential of Ni++|Ni\n",
+ "\n",
+ "#calculation\n",
+ "dV=V_Ni-V_Cd\n",
+ "C_Ni=10**-3\n",
+ "C_Cd=0.5\n",
+ "n=2 #Net electron exchange in Redox reaction\n",
+ "V=-dV-(0.0592*math.log10(C_Ni/C_Cd)/n)\n",
+ "\n",
+ "#Result\n",
+ "print\"Standard Cell potential is \",dV,\"V\"\n",
+ "print\"Net EMF is \",round(V,3),\"V\"\n",
+ "if V<0:\n",
+ " print\"Ni is reduced & Cd is oxidised\"\n",
+ "else:\n",
+ " print\"Cd is reduced & Ni is oxidised\"\n",
+ "\n",
+ "\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Standard Cell potential is 0.153 V\n",
+ "Net EMF is -0.073 V\n",
+ "Ni is reduced & Cd is oxidised\n"
+ ]
+ }
+ ],
+ "prompt_number": 8
+ },
+ {
+ "cell_type": "heading",
+ "level": 3,
+ "metadata": {},
+ "source": [
+ "Example 17.2 Page No 637"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Rate of Oxidation Computation\n",
+ "\n",
+ "#Given\n",
+ "#Activation polarisation data for Zn\n",
+ "VZn_Zn2=-0.763\n",
+ "iZn=10**-7\n",
+ "beta_Zn=0.09\n",
+ "#For H2\n",
+ "iH2=10**-10\n",
+ "VH_H2=0\n",
+ "beta_H2=-0.08\n",
+ "\n",
+ "#calculation\n",
+ "#Part i\n",
+ "ic=10**((VH_H2-VZn_Zn2-(beta_H2*math.log10(iH2))+(beta_Zn*math.log10(iZn)))/(beta_Zn-beta_H2))\n",
+ "n=2 #Exchange of 2 electrons\n",
+ "F=96500 #Faradays constant\n",
+ "r=ic/(n*F)\n",
+ "#Part ii\n",
+ "Vc=VH_H2+(beta_H2*log10(ic/iH2))\n",
+ "\n",
+ "#Result\n",
+ "print\"i) Rate of oxiadation is\",round(r,12),\"mol/cm**2-s\"\n",
+ "print\"ii) Corrosion potential is\",round(Vc,3),\"V\"\n",
+ "\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "i) Rate of oxiadation is 6.18e-10 mol/cm**2-s\n",
+ "ii) Corrosion potential is -0.486 V\n"
+ ]
+ }
+ ],
+ "prompt_number": 12
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [],
+ "language": "python",
+ "metadata": {},
+ "outputs": []
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file