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author | kinitrupti | 2017-05-12 18:40:35 +0530 |
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committer | kinitrupti | 2017-05-12 18:40:35 +0530 |
commit | d36fc3b8f88cc3108ffff6151e376b619b9abb01 (patch) | |
tree | 9806b0d68a708d2cfc4efc8ae3751423c56b7721 /Physical_Chemistry_by_D._Farrington/Chapter20.ipynb | |
parent | 1b1bb67e9ea912be5c8591523c8b328766e3680f (diff) | |
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diff --git a/Physical_Chemistry_by_D._Farrington/Chapter20.ipynb b/Physical_Chemistry_by_D._Farrington/Chapter20.ipynb new file mode 100644 index 00000000..c3593a82 --- /dev/null +++ b/Physical_Chemistry_by_D._Farrington/Chapter20.ipynb @@ -0,0 +1,220 @@ +{ + "cells": [ + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "# Chapter20 Macromolecules" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 20.1, Page no.76" + ] + }, + { + "cell_type": "code", + "execution_count": 2, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "average molecular weight of this polystrene = 287.48 Kg moleˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "R=0.082 # l−atm degˆ−1 moleˆ−1 \n", + "T=25 #C \n", + "V=85*10**-6 # l−atm gˆ−1 \n", + "#CALCULATIONS \n", + "M=R*(273+T)/V \n", + "#RESULTS\n", + "M=M/10**3\n", + "M=round(M,2)\n", + "print 'average molecular weight of this polystrene =',M,'Kg moleˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 20.2, Page no.76" + ] + }, + { + "cell_type": "code", + "execution_count": 3, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "maximum molecular weight = 69.41 Kg moleˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "from math import pi\n", + "#initialisation of variables\n", + "T=20 #C \n", + "v=0.01005 # poise \n", + "N=6*10**23 # molecules\n", + "D=7.8*10** -7 \n", + "#CALCULATIONS \n", + "M=4*pi*N/(3*0.75*(D*N*6*pi*v/(8.31*10**7*(273+T))) **3) \n", + "#RESULTS\n", + "M=M/10**3\n", + "M=round(M,2)\n", + "print 'maximum molecular weight =',M,'Kg moleˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 20.3, Page no.77" + ] + }, + { + "cell_type": "code", + "execution_count": 7, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "time = 1.04 * 10**-12 sec\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "w=2.82*10**7 \n", + "t2=70 #min \n", + "t1=60 #min \n", + "r2=6.731 #cm \n", + "r1=5.949 #cm \n", + "#CALCULATIONS \n", + "s=2.303*math.log10(r2/r1)/(w*t2*t1)\n", + "#RESULTS\n", + "s=s*10**12\n", + "s=round(s,2)\n", + "print 'time =',s,'* 10**-12 sec'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 20.4, Page no.77" + ] + }, + { + "cell_type": "code", + "execution_count": 13, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "molecular weight serum albium = 63.92 Kg mole ˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "R=8.31*10**7 # ergs degˆ−1 moleˆ−1 \n", + "T=20 #C \n", + "s=4.3*10** -13 # sec \n", + "D=6.15*10** -7 #cmˆ2 secˆ−1 \n", + "d=0.9982 #g/ cc \n", + "v=0.735 #cmˆ3 gˆ−1 \n", + "#CALCULATIONS\n", + "M=R*(273+T)*s/(D*(1-d*v)) \n", + "#RESULTS\n", + "M=M/10**3\n", + "M=round(M,2)\n", + "print 'molecular weight serum albium =',M,'Kg mole ˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 20.5, Page no.78" + ] + }, + { + "cell_type": "code", + "execution_count": 14, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "Molecular weight = 210.98 g moleˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "K=3.7*10** -4 \n", + "a=0.62 \n", + "iv=0.74 \n", + "#CALCULATIONS \n", + "M=(iv/K)**(1/a) \n", + "#RESULTS\n", + "M=M/10**3\n", + "M=round(M,2)\n", + "print 'Molecular weight =',M,'g moleˆ−1'" + ] + } + ], + "metadata": { + "anaconda-cloud": {}, + "kernelspec": { + "display_name": "Python [Root]", + "language": "python", + "name": "Python [Root]" + }, + "language_info": { + "codemirror_mode": { + "name": "ipython", + "version": 2 + }, + "file_extension": ".py", + "mimetype": "text/x-python", + "name": "python", + "nbconvert_exporter": "python", + "pygments_lexer": "ipython2", + "version": "2.7.11" + } + }, + "nbformat": 4, + "nbformat_minor": 0 +} |