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author | kinitrupti | 2017-05-12 18:40:35 +0530 |
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committer | kinitrupti | 2017-05-12 18:40:35 +0530 |
commit | d36fc3b8f88cc3108ffff6151e376b619b9abb01 (patch) | |
tree | 9806b0d68a708d2cfc4efc8ae3751423c56b7721 /Physical_Chemistry_by_D._Farrington/Chapter12_Chemical_Kinetics.ipynb | |
parent | 1b1bb67e9ea912be5c8591523c8b328766e3680f (diff) | |
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diff --git a/Physical_Chemistry_by_D._Farrington/Chapter12_Chemical_Kinetics.ipynb b/Physical_Chemistry_by_D._Farrington/Chapter12_Chemical_Kinetics.ipynb deleted file mode 100644 index 374d997a..00000000 --- a/Physical_Chemistry_by_D._Farrington/Chapter12_Chemical_Kinetics.ipynb +++ /dev/null @@ -1,215 +0,0 @@ -{ - "cells": [ - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "# Chapter12 Chemical Kinetics" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example 12.1, Page no.48" - ] - }, - { - "cell_type": "code", - "execution_count": 3, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "fraction of nitrogen pentoxide remain unreacted after 1 hour= 0.311\n" - ] - } - ], - "source": [ - "import math\n", - "#initialisation of variables\n", - "Vs=23.95 #ml \n", - "Ve=34.75 #ml \n", - "#CALCULATIONS \n", - "fr=(Ve-Vs)/Ve \n", - "#RESULTS \n", - "fr=round(fr,3)\n", - "print 'fraction of nitrogen pentoxide remain unreacted after 1 hour=',fr" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example 12.2, Page no.48" - ] - }, - { - "cell_type": "code", - "execution_count": 4, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "fraction remained undecomposed 0.5\n" - ] - } - ], - "source": [ - "import math\n", - "#initialisation of variables\n", - "Ps=200.0 #mm \n", - "Pe=390.0 #mm \n", - "Pt=300.0 #mm \n", - "t=500.0 #sec\n", - "Pe1=400.0 #mm \n", - "#CALCULATIONS \n", - "r= (Pe1-Pt)/(Pe1 -Ps)\n", - "#RESULTS\n", - "print 'fraction remained undecomposed',r" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example 12.3, Page no.49" - ] - }, - { - "cell_type": "code", - "execution_count": 5, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "time of residence of gas= 25.0 sec\n" - ] - } - ], - "source": [ - "import math\n", - "#initialisation of variables\n", - "V=1200.0 #ml\n", - "V1=100.0 #ml\n", - "t=300.0 # sec\n", - "#CALCULATIONS\n", - "r=V/t\n", - "t1=V1/r\n", - "#RESULTS \n", - "print 'time of residence of gas=',t1,'sec'" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example 12.4, Page no.49" - ] - }, - { - "cell_type": "code", - "execution_count": 6, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "k= 0.107 lit molˆ−1 secˆ−1\n" - ] - } - ], - "source": [ - "import math\n", - "#initialisation of variables\n", - "y=0.550\n", - "x=2400.0\n", - "d=0.00494\n", - "#CALCULATIONS\n", - "s=y/x\n", - "k=s*2.303/d\n", - "#RESULTS \n", - "k=round(k,3)\n", - "print 'k=',k,'lit molˆ−1 secˆ−1'" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example 12.7, Page no.50" - ] - }, - { - "cell_type": "code", - "execution_count": 7, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "second order rate for this constant= 0.0061 lit molˆ−1 secˆ−1\n" - ] - } - ], - "source": [ - "import math\n", - "from math import sqrt,pi\n", - "#initialisation of variables\n", - "T=393.7 #C \n", - "k=2.6*10** -4 # l i t molˆ−1 secˆ−1 \n", - "R=1.987 # cal moleˆ−1 Kˆ−1 \n", - "E=45.6 # kcal moleˆ−1 \n", - "wl=3.5 #A \n", - "N=6*10**23 # molecules \n", - "R1=8.31*10 # ergs moleˆ−1 Kˆ−1 \n", - "M=127.9 #g moleˆ−1 \n", - "#CALCULATIONS \n", - "k=2*10**2*N*sqrt(pi*R1*(273.1+T)/M)*(wl*10**-8)**2*math.exp(-E*10**3/(R*(273.1+T)))\n", - "#RESULTS\n", - "k=round(k,4)\n", - "print 'second order rate for this constant=',k,'lit molˆ−1 secˆ−1'" - ] - } - ], - "metadata": { - "anaconda-cloud": {}, - "kernelspec": { - "display_name": "Python [Root]", - "language": "python", - "name": "Python [Root]" - }, - "language_info": { - "codemirror_mode": { - "name": "ipython", - "version": 2 - }, - "file_extension": ".py", - "mimetype": "text/x-python", - "name": "python", - "nbconvert_exporter": "python", - "pygments_lexer": "ipython2", - "version": "2.7.11" - } - }, - "nbformat": 4, - "nbformat_minor": 0 -} |