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-{
- "metadata": {
- "name": "Chapter8"
- },
- "nbformat": 3,
- "nbformat_minor": 0,
- "worksheets": [
- {
- "cells": [
- {
- "cell_type": "heading",
- "level": 1,
- "metadata": {},
- "source": [
- "Chapter 8:Many Electron Atoms"
- ]
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 8.1 Page 248"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#initiation of variable\n",
- "hc=1240.0*10**-9;Rinfi=1.097*10**7;Z=11; #for sodium atom;and other constants in MeV\n",
- "\n",
- "#calculation\n",
- "delE=3*hc*Rinfi*(Z-1)**2/4.0 #change in energy\n",
- "\n",
- "#result\n",
- "print\"The energy of the Ka x-ray of the sodium atom in KeV.is\",round(delE/10**3,3);\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "The energy of the Ka x-ray of the sodium atom in KeV.is 1.02\n"
- ]
- }
- ],
- "prompt_number": 1
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 8.2 Page 249"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#initiation of variable\n",
- "EKa=21.990;EKb=25.145;EK=25.514 #all the values are in KeV\n",
- "\n",
- "#calcualtion\n",
- "ELo=EKb-EKa;\n",
- "\n",
- "#result\n",
- "print\"The energy of La of X-ray in KeV.is\",round(ELo,3); #Energy of La X-ray\n",
- "\n",
- "#partb\n",
- "EL=-EK+EKa;\n",
- "\n",
- "#result\n",
- "print\"Hence the binding energy of the L electon in KeV.is\",round(EL,3); # for electron L electron"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "The enrgy of La of X-ray in KeV.is 3.155\n",
- "Hence the binding energy of the L electon in KeV.is -3.524\n"
- ]
- }
- ],
- "prompt_number": 2
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 8.3 Page 250"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#initiation of variable\n",
- "l=1.0; \n",
- "\n",
- "#calculation\n",
- "Lmax=l+l;Lmin=l-l;\n",
- "s=1.0/2; Smax=s+s;Smin=s-s;\n",
- "\n",
- "#result\n",
- "print\"Value of L ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n",
- "print\"Values of S are maxi,min\",Smax,Smin;\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "Value of L ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n",
- "Values of S are maxi,min 1.0 0.0\n"
- ]
- }
- ],
- "prompt_number": 5
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 8.4 Page 250"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#initiation of variable\n",
- "l=1.0; \n",
- "\n",
- "#calculation\n",
- "Lmax=l+l;Lmin=l-l;\n",
- "s=1.0/2; Smax=s+s;Smin=s-s;\n",
- "\n",
- "#result\n",
- "print\"Considering any two electrons,Value of L2e ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n",
- "print\"Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\"\n",
- "print\"Values of S are maxi,min\",Smax,Smin;\n",
- "print\"Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\";"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "Considering any two electrons,Value of L2e ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n",
- "Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\n",
- "Values of S are maxi,min 1.0 0.0\n",
- "Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\n"
- ]
- }
- ],
- "prompt_number": 6
- }
- ],
- "metadata": {}
- }
- ]
-} \ No newline at end of file