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author | kinitrupti | 2017-05-12 18:40:35 +0530 |
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committer | kinitrupti | 2017-05-12 18:40:35 +0530 |
commit | d36fc3b8f88cc3108ffff6151e376b619b9abb01 (patch) | |
tree | 9806b0d68a708d2cfc4efc8ae3751423c56b7721 /Advanced_Engineering_Chemistry__by_Dr._M.R._Senapati/Chapter_7.ipynb | |
parent | 1b1bb67e9ea912be5c8591523c8b328766e3680f (diff) | |
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diff --git a/Advanced_Engineering_Chemistry__by_Dr._M.R._Senapati/Chapter_7.ipynb b/Advanced_Engineering_Chemistry__by_Dr._M.R._Senapati/Chapter_7.ipynb deleted file mode 100755 index 229b5da3..00000000 --- a/Advanced_Engineering_Chemistry__by_Dr._M.R._Senapati/Chapter_7.ipynb +++ /dev/null @@ -1,431 +0,0 @@ -{ - "metadata": { - "name": "" - }, - "nbformat": 3, - "nbformat_minor": 0, - "worksheets": [ - { - "cells": [ - { - "cell_type": "heading", - "level": 1, - "metadata": {}, - "source": [ - "Chapter 7: Solid State" - ] - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 1, Page no: 209" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Solution\n", - "print \"Weiss indices \\t\\t\\t1/2, 2/3, infinity \\t2/3, 2, 1/3\"\n", - "print \"Reciprocal of Weiss indices 2, 3/2, 1/infinity \\t3/2, 1/2, 3\"\n", - "print \"Clear fractions\\t\\t\\t4, 3, 0 \\t3, 1, 6\"\n", - "print \"Miller indices \\t\\t\\t (430) \\t (316)\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Weiss indices \t\t\t1/2, 2/3, infinity \t2/3, 2, 1/3\n", - "Reciprocal of Weiss indices 2, 3/2, 1/infinity \t3/2, 1/2, 3\n", - "Clear fractions\t\t\t4, 3, 0 \t3, 1, 6\n", - "Miller indices \t\t\t (430) \t (316)\n" - ] - } - ], - "prompt_number": 3 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 2, Page no: 209" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "from math import sqrt\n", - "\n", - "\n", - "# Variable\n", - "a = 450 # pm\n", - "\n", - "# Solution\n", - "d220 = a / sqrt(2 ** 2 + 2 ** 2 + 0)\n", - "print \"Interplanar spacing\", int(d220)\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Interplanar spacing 159\n" - ] - } - ], - "prompt_number": 5 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 3, Page no: 209" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Solution\n", - "print \"Intercept \\t(a, b ,c)\\t\\t(a, 2b, c) \\t\\t(a, 2b, 2c) \\t\\t(infi, b, -c)\"\n", - "print \"Weiss indices\\t 1, 1, 1 \\t\\t 1, 2, 1 \\t\\t 1, 2, 2 \\t\\t infi, 1, -1\"\n", - "print \"Reciprocals \\t 1, 1, 1 \\t\\t 1, 1/2, 1 \\t\\t 1, 1/2, 1/2\\t\\t 0, 1, -1\"\n", - "print \"Miller indicec\\t (111) \\t\\t (212) \\t\\t (211) \\t\\t (011)\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Intercept \t(a, b ,c)\t\t(a, 2b, c) \t\t(a, 2b, 2c) \t\t(infi, b, -c)\n", - "Weiss indices\t 1, 1, 1 \t\t 1, 2, 1 \t\t 1, 2, 2 \t\t infi, 1, -1\n", - "Reciprocals \t 1, 1, 1 \t\t 1, 1/2, 1 \t\t 1, 1/2, 1/2\t\t 0, 1, -1\n", - "Miller indicec\t (111) \t\t (212) \t\t (211) \t\t (011)\n" - ] - } - ], - "prompt_number": 7 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 4, Page no: 209" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Variables\n", - "rNa = 0.98 * 10 ** - 10 # m\n", - "rCl = 1.81 * 10 ** - 10 # m\n", - "\n", - "# Solution\n", - "rr = rNa / rCl\n", - "print \"When the radius ration is\", \"{:.2f}\".format(rr),\n", - "print \", the coordination number is 6.\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "When the radius ration is 0.54 , the coordination number is 6.\n" - ] - } - ], - "prompt_number": 9 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 5, Page no: 210" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Variables\n", - "rLi = 68 # pm\n", - "rF = 136. # pm\n", - "\n", - "# Solution\n", - "rr = rLi / rF\n", - "print \"Radius ratio =\", rr\n", - "print \"The structure of LiF is scc and C.N of Li+ = 6\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Radius ratio = 0.5\n", - "The structure of LiF is scc and C.N of Li+ = 6\n" - ] - } - ], - "prompt_number": 2 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 6, Page no: 210" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "from math import sin\n", - "\n", - "\n", - "# Variables\n", - "lamda = 2 * 10 ** - 10 # m\n", - "theta = 30 # degrees\n", - "\n", - "# Solution\n", - "print \"For first-order reflection\"\n", - "d = lamda / (2 * sin(theta))\n", - "dist = 2 * d\n", - "print \"Hence, distance between planes is\", \"{:.0e}\".format(abs(dist)), \"m\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "For first-order reflection\n", - "Hence, distance between planes is 2e-10 m\n" - ] - } - ], - "prompt_number": 3 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 7, Page no: 210" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "from math import sqrt\n", - "\n", - "\n", - "# Variables\n", - "r = 174.6 # pm\n", - "\n", - "# Solution\n", - "a = r * sqrt(8)\n", - "print \"For 200 plane: h = 2, k = 0, l = 0\"\n", - "d200 = a / sqrt(2 ** 2)\n", - "print \"d200 =\", \"{:.1f}\".format(d200), \"pm\"\n", - "print \"For 200 plane: h = 2, k = 2, l = 0\"\n", - "d220 = a / sqrt(2 ** 2 + 2 ** 2)\n", - "print \"d220 =\", d220, \"pm\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "For 200 plane: h = 2, k = 0, l = 0\n", - "d200 = 246.9 pm\n", - "For 200 plane: h = 2, k = 2, l = 0\n", - "d220 = 174.6 pm\n" - ] - } - ], - "prompt_number": 17 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 8, Page no: 210" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Constant\n", - "N = 6.023 * 10 ** 23\n", - "\n", - "# Variables\n", - "wt = 55.6\n", - "p = 0.29 # nm\n", - "n = 2\n", - "\n", - "# Solution\n", - "print \"For BCC pattern,\"\n", - "print \"number of atoms per unit cell = 2\"\n", - "d = n * (wt * 10 ** -3) / (N * (p * 10 ** - 9) ** 3)\n", - "print \"Density of the metal is\", \"{:.2e}\".format(d), \"kg / m^3\"\n", - "print \"Number of nearest enighbour for BCC = 8\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "For BCC pattern,\n", - "number of atoms per unit cell = 2\n", - "Density of the metal is 7.57e+03 kg / m^3\n", - "Number of nearest enighbour for BCC = 8\n" - ] - } - ], - "prompt_number": 4 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 9, Page no: 210" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Solution\n", - "print \"Intercept \\t2a/2, 2b, c/3\"\n", - "print \"Weiss indices\\t1, 2, 1/3\"\n", - "print \"Reciprocals \\t1, 1/2, 3\"\n", - "print \"Miller indices\\t (216)\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Intercept \t2a/2, 2b, c/3\n", - "Weiss indices\t1, 2, 1/3\n", - "Reciprocals \t1, 1/2, 3\n", - "Miller indices\t (216)\n" - ] - } - ], - "prompt_number": 19 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 10, Page no: 211" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "# Constant\n", - "N = 6.023 * 10 ** 23\n", - "\n", - "# Variables\n", - "D = 0.53 # g / cm ^ 3\n", - "MM = 6.94 # g / mol\n", - "n = 2\n", - "\n", - "# Solution\n", - "print \"For BCC pattern,\"\n", - "print \"number of atoms per unit cell = 2\"\n", - "V = D * N / (n * MM)\n", - "V = 1 / V\n", - "print \"Volume of a unit cell of lithium metal is\", \"{:.2e}\".format(V), \"cc\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "For BCC pattern,\n", - "number of atoms per unit cell = 2\n", - "Volume of a unit cell of lithium metal is 4.35e-23 cc\n" - ] - } - ], - "prompt_number": 23 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Problem 11, Page no: 211" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "from math import sqrt\n", - "\n", - "\n", - "print \"AB remain in BCC structure if the edge length is a then body diagonal\",\n", - "print \"is root(3)a\"\n", - "print \"root(3)a = 2(r+ + r-)\"\n", - "A = (sqrt(3) * 0.4123 - 2 * 0.81) / 2\n", - "print \"A+ =\", \"{:.2f}\".format(A), \"nm\"\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "AB remain in BCC structure if the edge length is a then body diagonal is root(3)a\n", - "root(3)a = 2(r+ + r-)\n", - "A+ = -0.45 nm\n" - ] - } - ], - "prompt_number": 25 - } - ], - "metadata": {} - } - ] -}
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