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+{
+"cells": [
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "# Chapter 15: THERMAL PROPERTIES"
+ ]
+ },
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.1: Debye_temperature_of_aluminium.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.1: Page-323 (2010)\n",
+"k = 1.38e-023; // Boltzmann constant, J/K\n",
+"h = 6.626e-034; // Planck's constant, Js\n",
+"f_D = 64e+011; // Debye frequency for Al, Hz\n",
+"theta_D = h*f_D/k; // Debye temperature, K\n",
+"printf('\nThe Debye temperature of aluminium = %5.1f K', theta_D);\n",
+"\n",
+"// Result\n",
+"// The Debye temperature of aluminium = 307.3 K "
+ ]
+ }
+,
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.2: Lattice_specific_heat_of_carbo.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.2: Page-323 (2010)\n",
+"N = 6.02e+026; // Avogadro's number, per kmol\n",
+"k = 1.38e-023; // Boltzmann constant, J/K\n",
+"h = 6.626e-034; // Planck's constant, Js\n",
+"f_D = 40.5e+012; // Debye frequency for Al, Hz\n",
+"T = 30; // Temperature of carbon, Ks\n",
+"theta_D = h*f_D/k; // Debye temperature, K\n",
+"C_l = 12/5*%pi^4*N*k*(T/theta_D)^3; // Lattice specific heat of carbon, J/k-mol/K\n",
+"printf('\nThe lattice specific heat of carbon = %4.2f J/k-mol/K', C_l);\n",
+"\n",
+"// Result\n",
+"// The lattice specific heat of carbon = 7.13 J/k-mol/K "
+ ]
+ }
+,
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.3: Einstein_frequency_for_Cu.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.3: Page-323 (2010)\n",
+"k = 1.38e-023; // Boltzmann constant, J/K\n",
+"h = 6.626e-034; // Planck's constant, Js\n",
+"theta_E = 1990; // Einstein temperature of Cu, K\n",
+"f_E = k*theta_E/h; // Einstein frequency for Cu, K\n",
+"printf('\nThe Einstein frequency for Cu = %4.2e Hz', f_E);\n",
+"printf('\nThe frequency falls in the near infrared region');\n",
+"\n",
+"// Result\n",
+"// The Einstein frequency for Cu = 4.14e+013 Hz\n",
+"// The frequency falls in the near infrared region "
+ ]
+ }
+,
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.4: Electronic_and_lattice_heat_capacities_for_Cu.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.4: Page-323 (2010)\n",
+"e = 1.6e-019; // Energy equivalent of 1 eV, J/eV\n",
+"N = 6.02e+023; // Avogadro's number, per mol\n",
+"T = 0.05; // Temperature of Cu, K\n",
+"E_F = 7; // Fermi energy of Cu, eV\n",
+"k = 1.38e-023; // Boltzmann constant, J/K\n",
+"h = 6.626e-034; // Planck's constant, Js\n",
+"theta_D = 348; // Debye temperature of Cu, K\n",
+"C_e = %pi^2*N*k^2*T/(2*E_F*e); // Electronic heat capacity of Cu, J/mol/K\n",
+"C_V = 12/5*%pi^4*N*k*(T/theta_D)^3; // Lattice heat capacity of Cu, J/mol/K\n",
+"printf('\nThe electronic heat capacity of Cu = %4.2e J/mol/K', C_e);\n",
+"printf('\nThe lattice heat capacity of Cu = %4.2e J/mol/K', C_V);\n",
+"\n",
+"// Result\n",
+"// The electronic heat capacity of Cu = 2.53e-005 J/mol/K\n",
+"// The lattice heat capacity of Cu = 5.76e-009 J/mol/K "
+ ]
+ }
+,
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.5: Einstein_lattice_specific_heat.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.5: Page-324 (2010)\n",
+"T = 1; // For simplicity assume temperature to be unity, K\n",
+"R = 1; // For simplicity assume molar gas constant to be unity, J/mol/K\n",
+"theta_E = T; // Einstein temperature, K\n",
+"C_V = 3*R*(theta_E/T)^2*exp(theta_E/T)/(exp(theta_E/T)-1)^2; // Einstein lattice specific heat, J/mol/K\n",
+"printf('\nThe Einstein lattice specific heat, C_v = %4.2f X 3R', C_V/3);\n",
+"\n",
+"// Result\n",
+"// The Einstein lattice specific heat, C_v = 0.92 X 3R"
+ ]
+ }
+,
+{
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 15.6: Molar_electronic_heat_capacity_of_zinc.sci"
+ ]
+ },
+ {
+"cell_type": "code",
+ "execution_count": null,
+ "metadata": {
+ "collapsed": true
+ },
+ "outputs": [],
+"source": [
+"// Scilab Code Ex15.6: Page-324 (2010)\n",
+"e = 1.6e-019; // Energy equivalent of 1 eV, J/eV\n",
+"v = 2; // Valency of Zn atom\n",
+"N = v*6.02e+023; // Avogadro's number, per mol\n",
+"T = 300; // Temperature of Zn, K\n",
+"E_F = 9.38; // Fermi energy of Zn, eV\n",
+"k = 1.38e-023; // Boltzmann constant, J/K\n",
+"h = 6.626e-034; // Planck's constant, Js\n",
+"C_e = %pi^2*N*k^2*T/(2*E_F*e); // Electronic heat capacity of Zn, J/mol/K\n",
+"printf('\nThe molar electronic heat capacity of zinc = %5.3f J/mol/K', C_e);\n",
+"\n",
+"// Result\n",
+"// The molar electronic heat capacity of zinc = 0.226 J/mol/K "
+ ]
+ }
+],
+"metadata": {
+ "kernelspec": {
+ "display_name": "Scilab",
+ "language": "scilab",
+ "name": "scilab"
+ },
+ "language_info": {
+ "file_extension": ".sce",
+ "help_links": [
+ {
+ "text": "MetaKernel Magics",
+ "url": "https://github.com/calysto/metakernel/blob/master/metakernel/magics/README.md"
+ }
+ ],
+ "mimetype": "text/x-octave",
+ "name": "scilab",
+ "version": "0.7.1"
+ }
+ },
+ "nbformat": 4,
+ "nbformat_minor": 0
+}