summaryrefslogtreecommitdiff
path: root/647/CH12/EX12.15
diff options
context:
space:
mode:
Diffstat (limited to '647/CH12/EX12.15')
-rwxr-xr-x647/CH12/EX12.15/Example12_15.sce47
1 files changed, 47 insertions, 0 deletions
diff --git a/647/CH12/EX12.15/Example12_15.sce b/647/CH12/EX12.15/Example12_15.sce
new file mode 100755
index 000000000..903734527
--- /dev/null
+++ b/647/CH12/EX12.15/Example12_15.sce
@@ -0,0 +1,47 @@
+clear;
+clc;
+
+// Example: 12.15
+// Page: 498
+
+printf("Example: 12.15 - Page: 498\n\n");
+
+// Solution
+
+//*****Data******//
+// Reaction: CH3COOH(l) + C2H5OH(l) --------> CH3COOC2H5(l) + H2O(l)
+T = 373.15;// [K]
+nCH3COOH_feed = 1;
+nC2H5OH_feed = 1;
+deltaHf_CH3COOH = -484.5;// [kJ]
+deltaHf_C2H5OH = -277.69;// [kJ]
+deltaHf_CH3COOC2H5 = -480;// [kJ]
+deltaHf_H2O = -285.83;// [kJ]
+deltaGf_CH3COOH = -389.9;// [kJ]
+deltaGf_C2H5OH = -174.78;// [kJ]
+deltaGf_CH3COOC2H5 = -332.2;// [kJ]
+deltaGf_H2O = -237.13;// [kJ]
+R = 8.314;// [J/mol K]
+//******************//
+
+deltaH_298 = deltaHf_CH3COOC2H5 + deltaHf_H2O - deltaHf_CH3COOH - deltaHf_C2H5OH;// [kJ]
+deltaG_298 = deltaGf_CH3COOC2H5 + deltaGf_H2O - deltaGf_CH3COOH - deltaGf_C2H5OH;// [kJ]
+T0 = 298;// [K]
+K_298 = exp(-(deltaG_298*1000/(R*T0)));
+K_373 = K_298*exp((deltaH_298*1000/R)*((1/T0) - (1/T)));
+// Let e be the degree of completion at equilibrium.
+// nCH3COOH_eqb = 1 - e;
+// nC2H5OH_eqb = 1 - e;
+// nCH3COOC2H5_eqb = e;
+// nH2O_eqb = e;
+// Total moles at equilibrium = 1 - e + 1 - e + e + e = 2
+// Mole fractions:
+// ySO2_eqb = (1 - e)/2
+// yO2_eqb = (1 - e)/2
+// ySO3_eqb = e/2
+// yAr_eqb = e/2
+// Sum of Stoichiometric Coeffecient:
+v = 1 + 1 - 1 - 1;
+deff('[y] = f(e)','y = K_373 - ((e/2)*(e/2))/(((1 - e)/2)*((1 - e)/2))');
+e = fsolve(0.5,f);
+printf("Mole fraction of ethyl acetate is %.3f",e/2); \ No newline at end of file