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diff --git a/635/CH5/EX5.4/Ch05Ex4.sci b/635/CH5/EX5.4/Ch05Ex4.sci new file mode 100755 index 000000000..f184a5c61 --- /dev/null +++ b/635/CH5/EX5.4/Ch05Ex4.sci @@ -0,0 +1,15 @@ +// Scilab Code Ex5.4 Number of Schottky imperfections in NaCl crystal Page-160 (2010)
+N = 6.023D23; // Avogadro's number
+k = 8.614D-5; // Boltzmann's constant, eV/K
+T = 27+273; // Absolute room temperature, K
+Ep = 2; // Energy required to remove a pair of Na+ and Cl- ions, electron-volt
+// Now Concentration of imperfections in a crystal is given by
+// n/N = exp(-Ep/(2*k*T)), solving for n
+n = N*exp(-Ep/(2*k*T)); // No. of Schottky imperfections present in NaCl crystal
+printf("\nNo. of Schottky imperfections present in NaCl crystal is : %4.2e", n);
+V = 26.83; // Volume of one mole of the crystal, cm cube
+n = n/V; // Number per mole volume of the crystal, per cm cube
+printf("\nConcentration of Schottky imperfections present in NaCl crystal is : %4.2e per cm cube", n);
+//Result
+// No. of Schottky imperfections present in NaCl crystal is : 9.42e+006
+// Concentration of Schottky imperfections present in NaCl crystal is : 3.51e+005 per cm cube
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