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diff --git a/479/CH14/EX14.4/Example_14_4.sce b/479/CH14/EX14.4/Example_14_4.sce new file mode 100755 index 000000000..883ee4d45 --- /dev/null +++ b/479/CH14/EX14.4/Example_14_4.sce @@ -0,0 +1,47 @@ +//Chemical Engineering Thermodynamics
+//Chapter 14
+//Thermodynamics of Chemical Reactions
+
+//Example 14.4
+clear;
+clc;
+
+//Given
+//Basis: 1Kgmole of C0
+//CO + (1/2)O2 - CO2
+//Whem mixture entered,their compositions are given as:
+n_CO = 1;//Kgmole
+del_H = -67636;//Standard heat of reaction in Kcal/Kgmole at 25 deg cel
+T1 = 95;//Temperature at which mixture entered in deg celsius
+T2 = 25;//Intermediate temperature in deg celsius
+//Mean specific heat values for the temperature between 25 and 95 deg celsius in Kcal/Kgmole are given as (from figure 14.4)(page no 303)
+Cpm_CO = 6.95;
+Cpm_O2 = 7.1;
+Cpm_N2 = 6.95;
+
+//To Calculate the theoretical flame temperature when both air and CO2 enter at 95 deg celsius
+n_O2 = 1;//Kgmole, as 100% excess air is given
+n_N2 = n_O2*(0.79/0.21);//Kgmole
+//After the rxn:
+n_CO2 = n_CO;//Kgmole
+n_O2_r = n_O2-(n_CO/2);//remaining Kgmole of O2
+//In equation 14.18 (page no 307) say: H_2-H_R = Ha, H_P-H_3 = Hb, Hc = del_H+Ha & Ht = Hc+Hb
+Ha = (n_CO*Cpm_CO + n_O2*Cpm_O2 + n_N2*Cpm_N2)*(T2-T1);//in Kcal/Kgmole
+Hc = del_H+Ha;//in Kcal/Kgmole
+//For calculating Hb let us assume the temperature as
+T = [530 1000 1650];//in deg celsius
+Cpm_CO2 = [10.85 12 12.75];//Mean specific heat of CO2 at the coresspondig temperature (from figure 14.4)
+Cpm_O2 = [7.55 7.8 8.3];//Mean specific heat of O2 at the coresspondig temperature (from figure 14.4)
+Cpm_N2 = [7.15 7.5 7.85];//Mean specific heat of N2 at the coresspondig temperature (from figure 14.4)
+for i = 1:3
+ Hb(i) = (n_CO2*Cpm_CO2(i)+n_O2_r*Cpm_O2(i)+n_N2*Cpm_N2(i))*(T(i)-T2);//in Kcal/Kgmole
+ Ht(i) = Hc+Hb(i);//in Kcal/Kgmole
+end
+clf;
+plot(T,Ht);
+xtitle(" ","Temperature, deg celsius","Ht in Kcal/Kgmole");
+a = get("current_axes");
+set(a,"x_location","origin");
+Tf = interpln([Ht';T],0);
+mprintf('The adiabatic temperature is read as %d degree celsius',Tf);
+//end
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