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Diffstat (limited to '3717/CH10/EX10.13/Ex10_13.sce')
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diff --git a/3717/CH10/EX10.13/Ex10_13.sce b/3717/CH10/EX10.13/Ex10_13.sce new file mode 100644 index 000000000..d4032dc51 --- /dev/null +++ b/3717/CH10/EX10.13/Ex10_13.sce @@ -0,0 +1,18 @@ +// Ex10_13 Page:224 (2014)
+clc;clear;
+e = 1.6e-019; // Charge on an electron, C
+epsilon_0 = 8.85e-012; // Absolute electric permittivity of free space, coulomb-square/N/Sq.m
+r_0 = 0.31e-009; // Equilibrium separation of Na+ and Cl- ions, m
+alpha = 1.748; // Madelung constant
+n = 9; // Repulsive exponent
+E_ion = 5; // Ionization energy of NaCl, eV
+V = -1*alpha*e^2/(4*3.14*epsilon_0*r_0*e)*(1-1/n); // Potential energy of Na+ and Cl- ions, eV
+E_ele = 1/2*V; // Electron affinity, eV
+E_trans = E_ion + E_ele; // Electron transfer energy, eV
+delta_E = E_trans/2; // Contribution per ion to the cohesive energy, eV
+E_cohesive = E_ele + delta_E; // Cohesive energy per NaCl atom, eV
+printf("\nThe cohesive energy per NaCl atom = %5.3f eV", E_cohesive);
+
+// Result
+// The cohesive energy per NaCl atom = -2.911 eV
+// The answers vary due to round off error
\ No newline at end of file |