diff options
Diffstat (limited to '3428/CH23/EX14.23.4')
| -rw-r--r-- | 3428/CH23/EX14.23.4/Ex14_23_4.sce | 19 |
1 files changed, 13 insertions, 6 deletions
diff --git a/3428/CH23/EX14.23.4/Ex14_23_4.sce b/3428/CH23/EX14.23.4/Ex14_23_4.sce index 75861f586..798ba3942 100644 --- a/3428/CH23/EX14.23.4/Ex14_23_4.sce +++ b/3428/CH23/EX14.23.4/Ex14_23_4.sce @@ -1,12 +1,19 @@ //Section-14,Example-2,Page no.-PC.75
//To calculate equilibrium composition of reaction mixture
clc;
-a_N2=1.00-x
-a_H2=3.00-(3*x)
-a_NH_3=2*x
+//a_N2=1.00-x //Equilibrium partial pressure of N_2(bar)
+//a_H2=3.00-(3*x) //Equilibrium partial pressure of H_2(bar)
+//a_NH_3=2*x //Equilibrium partial pressure of NH(bar)
//K=(2*x^2)/((1.00-x)*(3.00-3*x)^3)=977
x_1=(163.416+sqrt((163.416)^2-(4*81.208*81.208)))/(2*81.208)
x_2=(163.416-sqrt((163.416)^2-(4*81.208*81.208)))/(2*81.208)
-p_N2=1-x_2
-p_H2=3*(1-x_2)
-p_NH3=2*x_2
+disp(x_1,'1st value of K')
+disp(x_2,'2nd value of K')
+//since x_2<1,it is accepted as the value of x.
+p_N2=1-x_2 //bar
+disp(p_N2,'Equilibrium composition of N2(bar)')
+p_H2=3*(1-x_2) //bar
+disp(p_H2,'Equilibrium composition of H2(bar)')
+p_NH3=2*x_2 //bar
+disp(p_NH3,'Equilibrium composition of NH3(bar)')
+// It can be concluded that product NH3 dominate at equilibrium.
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