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Diffstat (limited to '1019/CH4/EX4.15/Example_4_15.sce')
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1 files changed, 30 insertions, 0 deletions
diff --git a/1019/CH4/EX4.15/Example_4_15.sce b/1019/CH4/EX4.15/Example_4_15.sce new file mode 100644 index 000000000..f779b7e24 --- /dev/null +++ b/1019/CH4/EX4.15/Example_4_15.sce @@ -0,0 +1,30 @@ +//Example 4.15
+clear;
+clc;
+
+//Given
+Cpw=75.42;//heat capacity of water in J K^-1 mol^-1
+T=263; //temperature in K
+P=1;//pressure in atm
+Cpi=37.20;//heat capacity of ice in J K^-1 mol^-1
+delHf=6008;// latent heat of fusion in J mol^-1
+mp=273;//melting point of water in K
+n=1;//moles of ice taken
+
+//To calculate the entropy change
+delS1=Cpw*log(mp/T);//entropy change during 1st step in J K^-1
+delS2=-delHf/mp;//entropy change during 2nd step in J K^-1
+delS3=Cpi*log(T/mp);//entropy change during final step in J K^-1
+delS=delS1+delS2+delS3;//total entropy change in J K^-1
+mprintf('Entropy change = %f J K^-1 mol^-1',delS);
+delH1=Cpw*(mp-T);//enthalpy change during 1st step in J
+delH2=-delHf;//enthalpy change during 2nd step in J
+delH3=Cpi*(T-mp);//entropy change during final step in J
+delHsys=delH1+delH2+delH3;//total enthalpy change in J
+delSsurr=-delHsys/T;//entropy change of surrounding in J K^-1
+delSuni=delS+delSsurr;//entropy of universe in J K^-1
+mprintf('\n Enthalpy change of the system = %f J mol^-1',delHsys);
+mprintf('\n Enthalpy change of the surrounding = %f J',-delHsys);
+mprintf('\n Entropy change of the surrounding = %f J K^-1',delSsurr);
+mprintf('\n Entropy change of the universe = %f J K^-1',delSuni);
+//end
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