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author | priyanka | 2015-06-24 15:03:17 +0530 |
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committer | priyanka | 2015-06-24 15:03:17 +0530 |
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diff --git a/611/CH8/EX8.4/Chap8_Ex4_R1.sce b/611/CH8/EX8.4/Chap8_Ex4_R1.sce new file mode 100755 index 000000000..560e8a63b --- /dev/null +++ b/611/CH8/EX8.4/Chap8_Ex4_R1.sce @@ -0,0 +1,30 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India.
+
+//Chapter-8,Example 4,Page 278
+//Title: Entropy departure using Beattie-Bridgman equation of state
+//================================================================================================================
+clear
+clc
+
+//INPUT
+T=100;//temperature of carbon dioxide in degree celsius
+P=10;//pressure of carbon dioxide in MPa
+B0=104.76*10^-6;//Beattie-Bridgman constant for carbon dioxide in m^3/mol
+b=72.35*10^-6;//Beattie-Bridgman constant for carbon dioxide in m^3/mol
+C=660.0;//Beattie-Bridgman constant for carbon dioxide in (m^3 K^3)/mol
+R=8.314;//universal gas constant in J/molK
+v=0.233*10^-3;//volume calculated in Example (8.3) in m^3/mol
+Z=0.751;//compressibility factor as calculated in Example (8.3) (no unit)
+
+//CALCULATION
+T=T+273.15;//conversion of temperature in K
+//calculation of entropy departure using Eq.(8.38) in J/molK
+dep_s=(R*log (Z))-(((B0*R)+((2*C*R)/(T^3)))*(1/v))+(((b*B0*R)-((2*C*B0*R)/(T^3)))*(1/(2*(v^2))))+((2*b*C*B0*R)/(3*(T^3)*(v^3)));
+
+//OUTPUT
+mprintf("\n The entropy departure for carbon dioxide using the Beattie-Bridgman equation of state = %f J/mol K\n",dep_s);
+
+
+//===============================================END OF PROGRAM===================================================
+
+//DISCLAIMER: THE PROBLEM STATEMENT MENTIONS THE TEMPERATURE TO BE 100 DEGREE CELSIUS, WHICH CORRESPONDS TO A TEMPERATURE OF 373.15K. HOWEVER, THE AUTHOR HAS EVALUATED THE ENTROPY DEPARTURE FOR A TEMPERATURE OF 313.15K, WHICH IS CLEARLY A PRINTING ERROR. THE CODE ABOVE HAS BEEN WRITTEN FOR THE TEMPERATURE OF 373.15K AS GIVEN IN THE PROBLEM STATEMENT.
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