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author | priyanka | 2015-06-24 15:03:17 +0530 |
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committer | priyanka | 2015-06-24 15:03:17 +0530 |
commit | b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (patch) | |
tree | ab291cffc65280e58ac82470ba63fbcca7805165 /593/CH6/EX6.1 | |
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initial commit / add all books
Diffstat (limited to '593/CH6/EX6.1')
-rwxr-xr-x | 593/CH6/EX6.1/ex6_1.sce | 27 |
1 files changed, 27 insertions, 0 deletions
diff --git a/593/CH6/EX6.1/ex6_1.sce b/593/CH6/EX6.1/ex6_1.sce new file mode 100755 index 000000000..140b7a475 --- /dev/null +++ b/593/CH6/EX6.1/ex6_1.sce @@ -0,0 +1,27 @@ +clear;
+//clc();
+
+// Example 6.1
+// Page: 108
+printf("Example-6.1 Page no.-108\n\n");
+
+//***Data***//
+T = 20;//[C]
+m_1 = 0;//[molal]
+m_2 = 1;//[molal]
+// The data given in the figure 6.2 , as reported in book, can be repersented with excellent accuracy by a simple data fitting equation
+//V = 1.0019+0.054668*m-0.000418*m^(2);
+// Where 'V' is( solution volume, liters per 1000g of water ) and 'm' is the molality of ethanol in water
+//The partial molal volume is obtained by differentiating the expression of the 'V' with respect to 'm'
+// v_ethanol = dV/dm = 0.054668-2*0.000418*m
+// So that at zero molality
+m = 0;//[molal]
+// the partial molal volume is
+v_1 = 0.054668-2*0.000418*m;//[L/mol]
+// and at
+m = 1;//[molal]
+v_2 = 0.054668-2*0.000418*m;//[L/mol]
+v_1 = v_1*1000;//[cm^(3)/mol]
+v_2 = v_2*1000;//[cm^(3)/mol]
+printf("Partial molal volume of ethanol in water at zero molality is %f cm^(3)/mol\n",v_1);
+printf(" Partial molal volume of ethanol in water at unity molality is %f cm^(3)/mol",v_2);
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