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authorprashantsinalkar2017-10-10 12:27:19 +0530
committerprashantsinalkar2017-10-10 12:27:19 +0530
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-rw-r--r--3856/CH11/EX11.5/Ex11_5.txt1
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+//Describe how you would prepare a phosphate buffer with a pH of seven point four
+
+//Example 11.5
+
+clc;
+
+clear;
+
+Ka1=7.5*10^-3; //Equilibrium consatnt for H3PO4= H+ +H2PO4-
+
+pKa1=-log10(Ka1); //minus logerithm of Ka1
+
+Ka2=6.2*10^-8; //Equilibrium consatnt for H2PO4-= H+ +HPO4--
+
+pKa2=-log10(Ka2); //minus logerithm of Ka2
+
+Ka3=4.8*10^-13; //Equilibrium consatnt for HPO4-- = H+ +PO3---
+
+pKa3=-log10(Ka3); //minus logerithm of Ka3
+
+pH=7.40; //pH of the required buffer solution
+
+C1=10^(pH-pKa2); //Concentratin of required solution to prepare buffer solution of pH of 7.40
+
+C=C1/1.0; //Ratio of the required solution to prepare buffer solution of pH of 7.40
+
+printf("Ratio of the required solution = %.2f The buffer is dissolve to disodium hydrogen phosphate and sodium dihydrogen phosphate in a mole ratio of 1.5:1.0 ",C);
+
diff --git a/3856/CH11/EX11.5/Ex11_5.txt b/3856/CH11/EX11.5/Ex11_5.txt
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+ Ratio of the required solution = 1.56 The buffer is dissolve to disodium hydrogen phosphate and sodium dihydrogen phosphate in a mole ratio of 1.5:1.0 \ No newline at end of file