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authorprashantsinalkar2017-10-10 12:27:19 +0530
committerprashantsinalkar2017-10-10 12:27:19 +0530
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parentb1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (diff)
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+////
+//Variable Declaration
+n = 3.0 //Number of moles of CO2
+Ti = 300 //Initial and final state Temeperatures of CO2, K
+Tf = 600
+pi = 1.00 //Initial and final state pressure of CO2, K
+pf = 3.00
+cpm = 27.98 //Specific heat of mercury, J/(mol.K)
+M = 200.59 //Molecualr wt of mercury, g/(mol)
+beta = 1.81e-4 //per K
+rho = 13.54 //Density of mercury, g/cm3
+R = 8.314 //Ideal Gas Constant, J/(mol.K)
+
+//Calcualtions
+dS1 = n*cpm*log(Tf/Ti)
+dS2 = n*(M/(rho*1e6))*beta*(pf-pi)*1e5
+dS = dS1 - dS2
+
+//Results
+printf("\n Entropy change of process is %4.1f J/(mol.K)",dS)
+
+printf("\n Ratio of pressure to temperature dependent term %3.1e\nhence effect of pressure dependent term is very less",dS2/dS1)
+
+printf("\n The above value is different as given in the text")
+
+