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authorprashantsinalkar2017-10-10 12:27:19 +0530
committerprashantsinalkar2017-10-10 12:27:19 +0530
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+//Example 5.24
+clear;
+clc;
+
+//Given
+p1=10;//vapour pressure of decane in Torr at temperature T1 K
+p2=400;//vapour pressure of decane in Torr at temperature T2 K
+T1=328.85;//initial temperature in K
+T2=423.75;//final temperature in K
+T=373;//temperature in K
+R=8.314;//gas constant in J K^-1 mol^-1
+
+//To determine the delHv,Tb,delSv
+delHv=(T1*T2*R*log(p2/p1))/94.9;//integrated form of clausius clapeyron equation
+delSv=delHv/T;//entrpoy change during vapourization in J K^-1 mol^-1
+Tb=((((R*2.303*log10(76))/delHv)+(1/T1))^(-1))+186;//boiling temperature in K
+mprintf('delHv = %f J mol^-1',delHv);
+mprintf('\n delSv = %f J K^-1 mol^-1',delSv);
+mprintf('\n Tb = %f K',Tb);
+//end \ No newline at end of file