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{
"cells": [
{
"cell_type": "markdown",
"metadata": {},
"source": [
"# Chapter23 Kinetics PhotoChemistry Radiation"
]
},
{
"cell_type": "markdown",
"metadata": {},
"source": [
"## Example 23.1, Page no.82"
]
},
{
"cell_type": "code",
"execution_count": 7,
"metadata": {
"collapsed": false
},
"outputs": [
{
"name": "stdout",
"output_type": "stream",
"text": [
"Entropy of activation = -10.6 cal degˆ−1 moleˆ−1\n"
]
}
],
"source": [
"import math\n",
"#initialisation of variables\n",
"k=9.12*10** -4 # secˆ−1 \n",
"H=25100 # cal moleˆ−1 \n",
"S=-10.6 # cal degˆ−1 moleˆ−1 \n",
"#RESULTS \n",
"print 'Entropy of activation =',S,'cal degˆ−1 moleˆ−1'"
]
},
{
"cell_type": "markdown",
"metadata": {},
"source": [
"## Example 23.2, Page no.82"
]
},
{
"cell_type": "code",
"execution_count": 8,
"metadata": {
"collapsed": false
},
"outputs": [
{
"name": "stdout",
"output_type": "stream",
"text": [
"quantum yield = 16.55\n"
]
}
],
"source": [
"import math\n",
"#initialisation of variables\n",
"h= 6.62*10** -27 # ergs / sec\n",
"c= 3*10**10 #cm/ sec\n",
"wl= 4358 #A\n",
"I= 14000 # ergs secˆ−1\n",
"p= 80.1 # percent\n",
"t= 1105 # sec\n",
"n= 0.075 # millimole \n",
"#CALCULATIONS \n",
"E= h*c/(wl*10**-8) \n",
"q= I*p*t/(100*E) \n",
"M= 6*10**23*n*10**-3 \n",
"P= M/q \n",
"#RESULTS \n",
"P=round(P,2)\n",
"print 'quantum yield =',P"
]
},
{
"cell_type": "markdown",
"metadata": {},
"source": [
"## Example 23.4, Page no.83"
]
},
{
"cell_type": "code",
"execution_count": 9,
"metadata": {
"collapsed": false
},
"outputs": [
{
"name": "stdout",
"output_type": "stream",
"text": [
"fraction of solar energy stored = 0.000912\n"
]
}
],
"source": [
"import math\n",
"#initialisation of variables\n",
"a=43560 # f t ˆ−2 \n",
"t= 500 #min dayˆ−1\n",
"E= 1000 # cal minˆ−1 f t ˆ−2\n",
"m= 2 # tons acreˆ−1\n",
"E1= 4000 # cal gramˆ−1\n",
"M= 9.07*10**5 #gram tonˆ−1\n",
"#CALCULATIONS \n",
"Sh= a*t*E*365.26\n",
"Hs= m*M*E1\n",
"r= Hs/Sh\n",
"#RESULTS\n",
"r=round(r,6)\n",
"print 'fraction of solar energy stored =',r"
]
},
{
"cell_type": "markdown",
"metadata": {},
"source": [
" ## Example 23.5, Page no.83"
]
},
{
"cell_type": "code",
"execution_count": 6,
"metadata": {
"collapsed": false
},
"outputs": [
{
"name": "stdout",
"output_type": "stream",
"text": [
"number of quanta = 1e+14\n",
"number of quanta = 7.14 * 10**12 molecules\n",
"grams per day= 4.55 *10**-9 gms\n"
]
}
],
"source": [
"import math\n",
"#initialisation of variables\n",
"h=6.625*10**-27 # ergs /mole\n",
"f=2.65*10**-5 # secˆ−1\n",
"c=3*10**10 #cm/ sec\n",
"t=2\n",
"N=6*10**23 # molecules\n",
"M=382 #gms\n",
"E1=750 # ergs \n",
"#CALCULATIONS \n",
"E=h*c/f \n",
"n1=E1/E \n",
"m=n1/(t*7) \n",
"G=m*M/N \n",
"#RESULTS\n",
"m=m*10**-12\n",
"m=round(m,2)\n",
"G=G*10**9\n",
"G=round(G,2)\n",
"print 'number of quanta =',n1\n",
"print 'number of quanta =',m,'* 10**12 molecules'\n",
"print 'grams per day=',G,'*10**-9 gms'"
]
}
],
"metadata": {
"anaconda-cloud": {},
"kernelspec": {
"display_name": "Python [Root]",
"language": "python",
"name": "Python [Root]"
},
"language_info": {
"codemirror_mode": {
"name": "ipython",
"version": 2
},
"file_extension": ".py",
"mimetype": "text/x-python",
"name": "python",
"nbconvert_exporter": "python",
"pygments_lexer": "ipython2",
"version": "2.7.11"
}
},
"nbformat": 4,
"nbformat_minor": 0
}
|
