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{
"metadata": {
"name": ""
},
"nbformat": 3,
"nbformat_minor": 0,
"worksheets": [
{
"cells": [
{
"cell_type": "heading",
"level": 1,
"metadata": {},
"source": [
"Chapter 8.: Statics and Band theory of Solids"
]
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.1, page no-208"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Fermi Energy of metals\n",
"\n",
"import math\n",
"# variable declaration\n",
"d_cu=8.96*10**3 # density of cu\n",
"a_cu=63.55 # Atomic weight of cu\n",
"d_z=7.14*10**3 # density of Zn \n",
"a_z=65.38 # Atomic weight of Zn\n",
"d_al=2700 # density of Al\n",
"a_al=27 # Atomic weight of Al \n",
"avg=6.022*10**26 # Avogadro's number \n",
"h=6.626*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # mass of an electrons\n",
"e=1.6*10**-19 # charge of an electron\n",
"\n",
"\n",
"\n",
"#(i)\n",
"\n",
"# Calculations\n",
"n_cu=d_cu*avg/a_cu\n",
"e_cu=(h**2/(8*m))*(3*n_cu/math.pi)**(2.0/3.0)\n",
"e_cu=e_cu/e\n",
"\n",
"#Result\n",
"print(\"\\n(i)For Cu\\nThe electron concentration in Cu is %.4f*10^28 per m^3\\nFermi energy at 0 k =%.4f eV \"%(n_cu*10**-28,e_cu))\n",
"\n",
"#(ii)\n",
"\n",
"# calculations\n",
"n_z=d_z*avg*2/a_z\n",
"e_z=(h**2/(8*m))*(3*n_z/math.pi)**(2.0/3.0)\n",
"e_z=e_z/e\n",
"\n",
"# Result\n",
"print(\"\\n(ii)For Zn\\nThe electron concentration in Zn is %.5f*10^28 per m^3\\nFermi energy at 0 k =%.2f eV \"%(n_z*10**-28,e_z))\n",
"\n",
"#(iii)\n",
"\n",
"# Calculations\n",
"n_al=d_al*avg*3/a_al\n",
"e_al=(h**2/(8*m))*(3*n_al/math.pi)**(2.0/3.0)\n",
"e_al=e_al/e\n",
"\n",
"#Result\n",
"print(\"\\n(iii)For Al\\nThe electron concentration in Al is %.3f*10^28 per m^3\\nFermi energy at 0 k =%.2f eV \"%(n_al*10**-28,e_al))\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"\n",
"(i)For Cu\n",
"The electron concentration in Cu is 8.4905*10^28 per m^3\n",
"Fermi energy at 0 k =7.0608 eV \n",
"\n",
"(ii)For Zn\n",
"The electron concentration in Zn is 13.15298*10^28 per m^3\n",
"Fermi energy at 0 k =9.45 eV \n",
"\n",
"(iii)For Al\n",
"The electron concentration in Al is 18.066*10^28 per m^3\n",
"Fermi energy at 0 k =11.68 eV \n"
]
}
],
"prompt_number": 9
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.2, page no-210"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Density of states for Cu\n",
"\n",
"import math\n",
"# variable declaration\n",
"avg=6.023*10**26 # avogadro's number\n",
"h=6.626*10**-34 # Planck's constant \n",
"m=9.1*10**-31 # mass of an electron\n",
"e=1.6*10**-19 # charge of an electron\n",
"n=8.4905*10**28 # sphere of radius\n",
"gam=6.82*10**27 # gamma\n",
"\n",
"# Calculations\n",
"ef=(h**2/(8*m))*(3*n/math.pi)**(2.0/3.0)\n",
"ef=ef/e\n",
"x=(gam*math.sqrt(ef))/2\n",
"\n",
"#Result\n",
"print(\"The density of states for Cu at the Fermi level for T = 0 K is %.0f*10^27 m^-3\"%(x*10**-27))\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The density of states for Cu at the Fermi level for T = 0 K is 9*10^27 m^-3\n"
]
}
],
"prompt_number": 11
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.3, page no-210"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Nordheims coeeficient\n",
"\n",
"import math\n",
"#Variable declaration\n",
"rni=63 # Resistivity of Ni\n",
"rcr=129 # Resistivity of Cr\n",
"k=1120 # Resistivity of 80% Ni + 20% Cr\n",
"\n",
"#Calculations\n",
"c=(k*10**-9)/(0.8*(1-0.8))\n",
"\n",
"#Result\n",
"print(\"The Nordheims coeeficient is %.0f *10^-6 Ohm-m\"%(c*10**6))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Nordheims coeeficient is 7 *10^-6 Ohm-m\n"
]
}
],
"prompt_number": 13
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.4, page no-211"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Conductivity of Al\n",
"\n",
"import math\n",
"#Variable declaaration\n",
"d=2700 # Density of Al\n",
"awt=27 # Atomic weight\n",
"t=10**-14 # Relaxation time\n",
"e=1.6*10**-19 # charge of an electron\n",
"m=9.1*10**-31 # mass of an electron\n",
"avg=6.022*10**26 # Avogadros number\n",
"\n",
"# calculation\n",
"n=avg*d*3/awt\n",
"sig=(n*t*e**2)/m\n",
"\n",
"#Result\n",
"print(\"The conductivity of Al is %.4f*10^7 ohm-m.\"%(sig*10**-7))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The conductivity of Al is 5.0823*10^7 ohm-m.\n"
]
}
],
"prompt_number": 15
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.5, page no-211"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"#Fermi distribution function\n",
"\n",
"import math\n",
"#variable declaration\n",
"e1=0.01 # difference between energy level to fermi level in eV\n",
"e=1.6*10**-19 # charge of an electron\n",
"ed=e*e1 # difference between energy level to fermi level in J\n",
"T=200 # Temperature\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"\n",
"# Calculations\n",
"E=1/(1+math.e**(ed/(T*k)))\n",
"print(\"The Fermi distribution function for energy E is %.4f\"%E)"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Fermi distribution function for energy E is 0.3590\n"
]
}
],
"prompt_number": 18
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.6, page no-212"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Fermi energy and fermi temperature\n",
"\n",
"import math\n",
"#variable declaration\n",
"v=0.86*10**6 # velocity of electron\n",
"m=9.11*10**-31 # mass of electron\n",
"e=1.6*10**-19 # electronic charge \n",
"k=1.38*10**-23 # Boltzmann's constant \n",
"\n",
"#calculations\n",
"E=(m*v**2)/2\n",
"E= math.floor(E*10**22)/10**22\n",
"T=E/k\n",
"\n",
"#Result\n",
"print(\"\\nThe fermi energy is %.3f*10^-19 J\\nThe Fermi Temperature Tf is %.2f*10^4 K\"%(E*10**19,T*10**-4))\n",
"# answer in the book for Temperature id 2.43 x 10^4"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"\n",
"The fermi energy is 3.368*10^-19 J\n",
"The Fermi Temperature Tf is 2.44*10^4 K\n"
]
}
],
"prompt_number": 25
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.7, page no-212"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# No of states lying between energy levels\n",
"\n",
"import math\n",
"# variable declaration\n",
"m=9.1*10**-31 # mass of electron\n",
"dE=0.01 # energy interval\n",
"h=6.63*10**-34 # planck's constant\n",
"eF=3.0 # Fermi energy\n",
"e=1.6*10**-19 # electronic charge\n",
"\n",
"#Calculations\n",
"E1=eF*e\n",
"E2=E1+e*dE\n",
"n=(4*math.pi*(2*m)**(1.5))/h**3\n",
"k=((2*0.3523/3)*((E2**(1.5)-(E1**(1.5)))))\n",
"n=n*k\n",
"\n",
"#Result\n",
"print(\"The number of states lying between the energy level is %.2f*10^25\"%(n*10**-25))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The number of states lying between the energy level is 4.14*10^25\n"
]
}
],
"prompt_number": 27
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.8, page no-214"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"#Fermi Velocity\n",
"\n",
"import math\n",
"#Variable declaration\n",
"Tf=24600 # Fermi temperature of the metal\n",
"m=9.11*10**-31 # mass of electron\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"\n",
"#Calculations\n",
"vf=math.sqrt(2*k*Tf/m)\n",
"\n",
"#Result\n",
"print(\"The Fermi Velocity is %.4f *10^6 m/s\"%(vf*10**-6))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Fermi Velocity is 0.8633 *10^6 m/s\n"
]
}
],
"prompt_number": 29
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.9, page no-214"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"#Fermi energy\n",
"\n",
"import math\n",
"#variable declaration\n",
"n=18.1*10**28 # elecron density of electron\n",
"h=6.62*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # mass of an electron\n",
"e=1.6*10**-19 # electronic charge\n",
"\n",
"#calculations\n",
"ef=((3*n/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"ef=ef/e\n",
"ef=math.ceil(ef*100)/100\n",
"\n",
"#Result\n",
"print(\"The Fermi energy at 0 K is %.2f eV \"%(ef))\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Fermi energy at 0 K is 11.68 eV \n"
]
}
],
"prompt_number": 40
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.10, page no-215"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"#Fermi energy \n",
"\n",
"import math\n",
"#variable declaration\n",
"n=18.1*10**28 # elecron density of electron\n",
"h=6.62*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # mass of an electron\n",
"e=1.6*10**-19 # electronic charge\n",
"\n",
"#calculations\n",
"ef=((3*n/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"ef=ef/e\n",
"ef=math.ceil(ef*100)/100\n",
"\n",
"#result\n",
"print(\"The Fermi energy at 0 K is %.2f eV \"%ef)\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Fermi energy at 0 K is 11.68 eV \n"
]
}
],
"prompt_number": 45
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.11, page no-215"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Temperature calculation\n",
"\n",
"import math\n",
"#variable declaration\n",
"e=1.6*10**-19 # electronic charge\n",
"Ed=0.5*e # difference between energy level to fermi level\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"x=0.01 # probability\n",
"\n",
"#Calculaations\n",
"T=Ed/(k*math.log((1/x)-1))\n",
"\n",
"#Result\n",
"print(\"Temperature at which there is 1%% probability that a state with 0.5 eV energy occupied above the Fermi energy level is %.1f K\"%T)\n",
"#answer is not matching with the answer given in the book"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"Temperature at which there is 1% probability that a state with 0.5 eV energy occupied above the Fermi energy level is 1261.6 K\n"
]
}
],
"prompt_number": 49
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.14, page no-218"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"#energies for the occupying of electrons\n",
"import math\n",
"\n",
"#variable declaration\n",
"ef=2.1 # Fermi energy\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"T=300 # Temperature\n",
"e=1.6*10**-19 # Electronic charge\n",
"\n",
"#calculations\n",
"\n",
"#(i)\n",
"p1=0.99 # probability\n",
"E1=ef+(k*T*math.log(-1+1/p1))/e\n",
"\n",
"#(ii)\n",
"p2=0.01 # probability\n",
"E2=ef+(k*T*math.log(-1+1/p2))/e\n",
"\n",
"#(iii)\n",
"p3=0.5 # probability\n",
"E3=ef+(k*T*math.log(-1+1/p3))/e\n",
"\n",
"#Result\n",
"\n",
"print(\"\\nThe energies for the occupying of electrons at %d K for the probability of %.2f are %.2f eV\"%(T,p1,E1))\n",
"\n",
"print(\"\\nThe energies for the occupying of electrons at %d K for the probability of %.2f are %.2f eV\"%(T,p2,E2))\n",
"\n",
"print(\"\\nThe energies for the occupying of electrons at %d K for the probability of %.2f are %.2f eV\"%(T,p3,E3))\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"\n",
"The energies for the occupying of electrons at 300 K for the probability of 0.99 are 1.98 eV\n",
"\n",
"The energies for the occupying of electrons at 300 K for the probability of 0.01 are 2.22 eV\n",
"\n",
"The energies for the occupying of electrons at 300 K for the probability of 0.50 are 2.10 eV\n"
]
}
],
"prompt_number": 53
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.15, page no-219"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Fermi distribution function\n",
"\n",
"import math\n",
"# Variable declarations\n",
"e=1.6*10**-19 # Electronic charge\n",
"ed=0.02*e # difference between energy level to fermi level\n",
"T1=200 # Temperature 1\n",
"T2=400 # Temperature 2\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"\n",
"#Calculations\n",
"fe1=1/(1+math.e**(ed/(k*T1)))\n",
"fe2=1/(1+math.e**(ed/(k*T2)))\n",
"\n",
"#Result\n",
"print(\"\\nThe Fermi distribution function for the given energy at %d K is %.5f\"%(T1,fe1))\n",
"print(\"\\nThe Fermi distribution function for the given energy at %d K is %.4f\"%(T2,fe2))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"\n",
"The Fermi distribution function for the given energy at 200 K is 0.23877\n",
"\n",
"The Fermi distribution function for the given energy at 400 K is 0.3590\n"
]
}
],
"prompt_number": 4
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.16, page no-220"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Fermi energy for given metal\n",
"\n",
"import math\n",
"#Variaable declaration\n",
"d=10500 # Density of the metal\n",
"avg=6.022*10**26 # Avogadro's number\n",
"awt=107.9 # Atomic weight of metal\n",
"h=6.62*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # mass of an electron\n",
"e=1.6*10**-19 # electronic charge\n",
"\n",
"#Calculattions\n",
"n=d*avg/awt\n",
"ef=((3*n/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"ef=ef/e\n",
"\n",
"#Result\n",
"print(\"The Fermi energy for given metal is %.1f eV \"%ef)\n"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The Fermi energy for given metal is 5.5 eV \n"
]
}
],
"prompt_number": 7
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.17, page no-221"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Fermi distribution function \n",
"\n",
"import math\n",
"#Variable declaration\n",
"e=1.6*10**-19 # electronic charge\n",
"ed=0.2*e # difference between energy level to Fermi level\n",
"T1=300 # Temperature 1\n",
"T2=1000 # Temperature 2\n",
"k=1.38*10**-23 # Boltzmann's constant\n",
"\n",
"#Calculations\n",
"fe1=1/(1+math.e**(ed/(k*T1)))\n",
"fe2=1/(1+math.e**(ed/(k*T2)))\n",
"\n",
"#Result\n",
"print(\"\\nThe Fermi distribution function for the given energy at %d K is %.7f\"%(T1,fe1))\n",
"print(\"\\nThe Fermi distribution function for the given energy at %d K is %.4f\"%(T2,fe2))\n",
"# Answer for 300 K is wrong in the book"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"\n",
"The Fermi distribution function for the given energy at 300 K is 0.0004395\n",
"\n",
"The Fermi distribution function for the given energy at 1000 K is 0.0896\n"
]
}
],
"prompt_number": 9
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.18, page no-221"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Free electrons concentration\n",
"\n",
"import math\n",
"#Variable declarations\n",
"h=6.62*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # Mass of electron\n",
"e=1.6*10**-19 # Charge of an electron\n",
"ef=3*e # Fermi Energy\n",
"\n",
"#Calculations\n",
"k=((3/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"k=ef/k\n",
"n=k**(1.5)\n",
"\n",
"#Result\n",
"print(\"The number of free electrons concentration in metal is %.2f *10^28 per cubic meter \"%(n*10**-28))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The number of free electrons concentration in metal is 2.36 *10^28 per cubic meter \n"
]
}
],
"prompt_number": 12
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.19, page no-221"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# Free electrons concentration in metal \n",
"\n",
"import math\n",
"#Variable declaration\n",
"h=6.626*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # Mass of electron\n",
"e=1.6*10**-19 # Charge of electron\n",
"ef=5.5*e # Fermi energy\n",
"\n",
"# Calculation\n",
"k=((3/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"k=ef/k\n",
"n=k**(1.5)\n",
"\n",
"#Result\n",
"print(\"The number of free electrons concentration in metal is %.3f * 10^28 per cubic meter \"%(n*10**-28))\n",
"#Answer is matching with the answer given in the book"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The number of free electrons concentration in metal is 5.837 * 10^28 per cubic meter \n"
]
}
],
"prompt_number": 31
},
{
"cell_type": "heading",
"level": 2,
"metadata": {},
"source": [
"Example 8.20, page no-221"
]
},
{
"cell_type": "code",
"collapsed": false,
"input": [
"# electrons concentration and termal velocity of electrons\n",
"\n",
"import math\n",
"#variable declaration\n",
"h=6.626*10**-34 # Planck's constant\n",
"m=9.1*10**-31 # mass of electron\n",
"e=1.6*10**-19 # charge of electron\n",
"ef=7*e # Fermi energy\n",
"\n",
"#calculations\n",
"k=((3/(8*math.pi))**(2.0/3.0))*((h**2)/(2*m))\n",
"k=ef/k\n",
"n=k**(1.5)\n",
"vth=math.sqrt(2*ef/m)\n",
"\n",
"#Result\n",
"print(\"The number of free electrons concentration in metal is %.2f *10^28 per cubic meter \"%(math.ceil(n*10**-28*10**2)/10**2))\n",
"print(\"\\nThe termal velocity of electrons in copper is %.3f *10^6 m/s\"%(math.floor(vth*10**-6*10**3)/10**3))"
],
"language": "python",
"metadata": {},
"outputs": [
{
"output_type": "stream",
"stream": "stdout",
"text": [
"The number of free electrons concentration in metal is 8.39 *10^28 per cubic meter \n",
"\n",
"The termal velocity of electrons in copper is 1.568 *10^6 m/s\n"
]
}
],
"prompt_number": 41
}
],
"metadata": {}
}
]
}
|