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+{
+ "metadata": {
+ "name": "Chapter8"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter 8:Many Electron Atoms"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 8.1 Page 248"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#initiation of variable\n",
+ "hc=1240.0*10**-9;Rinfi=1.097*10**7;Z=11; #for sodium atom;and other constants in MeV\n",
+ "\n",
+ "#calculation\n",
+ "delE=3*hc*Rinfi*(Z-1)**2/4.0 #change in energy\n",
+ "\n",
+ "#result\n",
+ "print\"The energy of the Ka x-ray of the sodium atom in KeV.is\",round(delE/10**3,3);\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The energy of the Ka x-ray of the sodium atom in KeV.is 1.02\n"
+ ]
+ }
+ ],
+ "prompt_number": 1
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 8.2 Page 249"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#initiation of variable\n",
+ "EKa=21.990;EKb=25.145;EK=25.514 #all the values are in KeV\n",
+ "\n",
+ "#calcualtion\n",
+ "ELo=EKb-EKa;\n",
+ "\n",
+ "#result\n",
+ "print\"The energy of La of X-ray in KeV.is\",round(ELo,3); #Energy of La X-ray\n",
+ "\n",
+ "#partb\n",
+ "EL=-EK+EKa;\n",
+ "\n",
+ "#result\n",
+ "print\"Hence the binding energy of the L electon in KeV.is\",round(EL,3); # for electron L electron"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The enrgy of La of X-ray in KeV.is 3.155\n",
+ "Hence the binding energy of the L electon in KeV.is -3.524\n"
+ ]
+ }
+ ],
+ "prompt_number": 2
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 8.3 Page 250"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#initiation of variable\n",
+ "l=1.0; \n",
+ "\n",
+ "#calculation\n",
+ "Lmax=l+l;Lmin=l-l;\n",
+ "s=1.0/2; Smax=s+s;Smin=s-s;\n",
+ "\n",
+ "#result\n",
+ "print\"Value of L ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n",
+ "print\"Values of S are maxi,min\",Smax,Smin;\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Value of L ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n",
+ "Values of S are maxi,min 1.0 0.0\n"
+ ]
+ }
+ ],
+ "prompt_number": 5
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 8.4 Page 250"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#initiation of variable\n",
+ "l=1.0; \n",
+ "\n",
+ "#calculation\n",
+ "Lmax=l+l;Lmin=l-l;\n",
+ "s=1.0/2; Smax=s+s;Smin=s-s;\n",
+ "\n",
+ "#result\n",
+ "print\"Considering any two electrons,Value of L2e ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n",
+ "print\"Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\"\n",
+ "print\"Values of S are maxi,min\",Smax,Smin;\n",
+ "print\"Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\";"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Considering any two electrons,Value of L2e ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n",
+ "Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\n",
+ "Values of S are maxi,min 1.0 0.0\n",
+ "Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\n"
+ ]
+ }
+ ],
+ "prompt_number": 6
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file