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diff --git a/Thermodynamics_for_Chemists/ch12.ipynb b/Thermodynamics_for_Chemists/ch12.ipynb new file mode 100755 index 00000000..a5fc4f25 --- /dev/null +++ b/Thermodynamics_for_Chemists/ch12.ipynb @@ -0,0 +1,181 @@ +{ + "metadata": { + "name": "", + "signature": "sha256:dbef979b458f64ee0bfe42675123da99553458bca4c9fa96996153ac4fc86f65" + }, + "nbformat": 3, + "nbformat_minor": 0, + "worksheets": [ + { + "cells": [ + { + "cell_type": "heading", + "level": 1, + "metadata": {}, + "source": [ + "Chapter 12 : Fugacity and Activity" + ] + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 12.1 Page No : 252" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "p1 = 50 \t\t\t#atm\n", + "p2 = 100 \t\t\t#atm\n", + "p3 = 200 \t\t\t#atm\n", + "p4 = 400 \t\t\t#atm\n", + "p5 = 800 \t\t\t#atm\n", + "p6 = 1000 \t\t\t#atm\n", + "r1 = 0.979\n", + "r2 = 0.967\n", + "r3 = 0.971\n", + "r4 = 1.061\n", + "r5 = 1.489\n", + "r6 = 1.834\n", + "\n", + "# Calculations\n", + "f1 = r1*p1\n", + "f2 = r2*p2\n", + "f3 = r3*p3\n", + "f4 = r4*p4\n", + "f5 = r5*p5\n", + "f6 = r6*p6\n", + "\n", + "# Results\n", + "print 'fugacity of nitrogen gas = %.2f atm'%(f1)\n", + "print ' fugacity of nitrogen gas = %.1f atm'%(f2)\n", + "print ' fugacity of nitrogen gas = %.1f atm'%(f3)\n", + "print ' fugacity of nitrogen gas = %.1f atm'%(f4)\n", + "print ' fugacity of nitrogen gas = %.f atm'%(f5)\n", + "print ' fugacity of nitrogen gas = %.f atm'%(f6)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "fugacity of nitrogen gas = 48.95 atm\n", + " fugacity of nitrogen gas = 96.7 atm\n", + " fugacity of nitrogen gas = 194.2 atm\n", + " fugacity of nitrogen gas = 424.4 atm\n", + " fugacity of nitrogen gas = 1191 atm\n", + " fugacity of nitrogen gas = 1834 atm\n" + ] + } + ], + "prompt_number": 1 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 12.2 Page No : 258" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "p1 = 50 \t\t\t#atm\n", + "p2 = 100 \t\t\t#atm\n", + "p3 = 200 \t\t\t#atm\n", + "p4 = 400 \t\t\t#atm\n", + "r1 = 0.98\n", + "r2 = 0.97\n", + "r3 = 0.98\n", + "r4 = 1.07\n", + "\n", + "# Calculations\n", + "f1 = p1*r1\n", + "f2 = p2*r1\n", + "f3 = p3*r3\n", + "f4 = p4*r4\n", + "\n", + "# Results\n", + "print 'fugacity of nitrogen gas = %.f atm'%(f1)\n", + "print ' fugacity of nitrogen gas = %.f atm'%(f2)\n", + "print ' fugacity of nitrogen gas = %.f atm'%(f3)\n", + "print ' fugacity of nitrogen gas = %.f atm'%(f4)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "fugacity of nitrogen gas = 49 atm\n", + " fugacity of nitrogen gas = 98 atm\n", + " fugacity of nitrogen gas = 196 atm\n", + " fugacity of nitrogen gas = 428 atm\n" + ] + } + ], + "prompt_number": 2 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 12.3 Page No : 260" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "p = 3.66 \t\t\t#atm\n", + "v = 6.01 \t\t\t#litre mole**-1\n", + "T = 0 \t\t\t#C\n", + "R = 0.082 \t\t\t#lit-atm mole**-1 K**-1\n", + "\n", + "# Calculations\n", + "f = p**2*v/(R*(273+T))\n", + "\n", + "# Results\n", + "print 'fugacity of liquid chlorine = %.2f atm'%(f)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "fugacity of liquid chlorine = 3.60 atm\n" + ] + } + ], + "prompt_number": 3 + }, + { + "cell_type": "code", + "collapsed": false, + "input": [], + "language": "python", + "metadata": {}, + "outputs": [] + } + ], + "metadata": {} + } + ] +}
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