summaryrefslogtreecommitdiff
path: root/The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb
diff options
context:
space:
mode:
Diffstat (limited to 'The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb')
-rw-r--r--The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb366
1 files changed, 366 insertions, 0 deletions
diff --git a/The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb b/The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb
new file mode 100644
index 00000000..22d57c08
--- /dev/null
+++ b/The_Elements_of_Physical_Chemistry_by_S._Glasstone/Chapter16.ipynb
@@ -0,0 +1,366 @@
+{
+ "metadata": {
+ "name": "",
+ "signature": "sha256:09be9a8e5f91af8fef0686407088d245fede9d0f128504215da1542a47c5c9a8"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter16-Hydrolysis and Neutralization"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex1-pg522"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "c= 0.01 ##M\n",
+ "T= 25. ##C\n",
+ "kw= 1.01*10**-14 \n",
+ "ka= 1.75*10**-5\n",
+ "##CALCULATIONS\n",
+ "x= math.sqrt(kw/(ka*c))\n",
+ "##RESULTS\n",
+ "print'%s %.1e %s'% ('Degree of hydrolysis = ',x,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Degree of hydrolysis = 2.4e-04 \n"
+ ]
+ }
+ ],
+ "prompt_number": 1
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex2-pg522"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "c= 0.01 ##M\n",
+ "ka= 1.75*10**-5\n",
+ "pkw= 14.\n",
+ "ka1= 1.79\n",
+ "##CALCULATIONS\n",
+ "pH= 0.5*pkw-0.5*math.log(ka)+0.5*math.log(c)-ka1\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('pH of solution = ',pH,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "pH of solution = 8.38 \n"
+ ]
+ }
+ ],
+ "prompt_number": 2
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex3-pg526"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variable\n",
+ "k1= 10**-14\n",
+ "c= 0.1 ##M\n",
+ "pH= 8.88\n",
+ "cH= 1.32*10**-9 ##gms\n",
+ "##CALCULATIONS\n",
+ "x= k1/(c*cH)\n",
+ "kh= c*x**2\n",
+ "##RESULTS\n",
+ "print'%s %.2e %s'% ('x = ',x,'')\n",
+ "print'%s %.2e %s'% ('\\n Hydrolysis constant = ',kh,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "x = 7.58e-05 \n",
+ "\n",
+ " Hydrolysis constant = 5.74e-10 \n"
+ ]
+ }
+ ],
+ "prompt_number": 3
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex4-pg527"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "c= 0.0156 ##M\n",
+ "ec= 111.5 ##ohm^-1 cm^2\n",
+ "ac= 99.9 ##ohm^-1 cm^2\n",
+ "ac1= 426. ##ohm^-1 cm^2\n",
+ "kw= 10**-14 \n",
+ "##CALCULATIONS\n",
+ "x= (ec-ac)/(ac1-ac)\n",
+ "kh= c*x**2/(1.-x)\n",
+ "kb= kw/kh\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('x = ',x,'')\n",
+ "print'%s %.1e %s'% ('\\n Hydrolysis constant = ',kh,'')\n",
+ "print'%s %.1e %s'% ('\\n Dissociation constant = ',kb,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "x = 0.04 \n",
+ "\n",
+ " Hydrolysis constant = 2.0e-05 \n",
+ "\n",
+ " Dissociation constant = 4.9e-10 \n"
+ ]
+ }
+ ],
+ "prompt_number": 4
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex5-pg531"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "pH= 7.\n",
+ "c1=1. ##M\n",
+ "c2= 0.155 ##M\n",
+ "c3= 0.25 ##m\n",
+ "c4= 0.05 ##M\n",
+ "c5= 0.62 ##M\n",
+ "pka= 7.21\n",
+ "##CALCULATIONS\n",
+ "ph1= pka+math.log10((c5+c4)/(c1-c4))\n",
+ "ph2= pka+math.log10((c2+c4)/(c3-c4))\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('final pH = ',ph1,'')\n",
+ "print'%s %.2f %s'% ('\\n final pH = ',ph2,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "final pH = 7.06 \n",
+ "\n",
+ " final pH = 7.22 \n"
+ ]
+ }
+ ],
+ "prompt_number": 5
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex6-pg535"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variablesclear\n",
+ "v1= -0.1252 ##volt\n",
+ "v2= 0.3636##volt\n",
+ "v3= 0.05915##volt\n",
+ "##CALCULATIONS\n",
+ "ph= (v1+v2)/v3\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('final pH = ',ph,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "final pH = 4.03 \n"
+ ]
+ }
+ ],
+ "prompt_number": 6
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex7-pg540"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variable\n",
+ "pki= 3.98\n",
+ "t1= 0.85 ##mm\n",
+ "t2= 0.15 ##mm\n",
+ "##CALCULATIONS\n",
+ "pH= pki+math.log10(t1/t2)\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('pH of the solution = ',pH,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "pH of the solution = 4.73 \n"
+ ]
+ }
+ ],
+ "prompt_number": 7
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex8-pg541"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "pki= 7.\n",
+ "t1= 3. ##drops\n",
+ "t2= 7. ##drops\n",
+ "##CALCULATIONS\n",
+ "pH= pki+math.log10(t1/t2)\n",
+ "##RESULTS\n",
+ "print'%s %.2f %s'% ('pH of the solution = ',pH,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "pH of the solution = 6.63 \n"
+ ]
+ }
+ ],
+ "prompt_number": 8
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Ex9-pg545"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "import math\n",
+ "##Intitalisation of variables\n",
+ "c= 0.1 ##N\n",
+ "ka= 5.75*10**-10 \n",
+ "##CALCULATIONS\n",
+ "cH= math.sqrt(c*ka)\n",
+ "pH= -math.log10(cH)\n",
+ "##RESULTS\n",
+ "print'%s %.2e %s'% ('cH = ',cH,'')\n",
+ "print'%s %.2f %s'% ('\\n pH of the solution = ',pH,'')\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "cH = 7.58e-06 \n",
+ "\n",
+ " pH of the solution = 5.12 \n"
+ ]
+ }
+ ],
+ "prompt_number": 9
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file
generated by cgit (git 2.34.1) at 2024-12-20 08:24:52 +0000