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-{
- "metadata": {
- "name": "",
- "signature": "sha256:732bbb076f615c901ca952cd233aa9a732520f864fa8a5b9d8200618c4707cce"
- },
- "nbformat": 3,
- "nbformat_minor": 0,
- "worksheets": [
- {
- "cells": [
- {
- "cell_type": "heading",
- "level": 1,
- "metadata": {},
- "source": [
- "Chapter 16 - Typical mechanisms and rate laws"
- ]
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 1 - pg 422"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#calculate the Rate constant\n",
- "#Initialization of variables\n",
- "import math\n",
- "P1=69.2 #mm\n",
- "P2=39.8#mm\n",
- "t=20 #min\n",
- "#calculations\n",
- "k=2.303*math.log10(P1/P2) /(t*60.)\n",
- "#results\n",
- "print '%s %.2e %s' %(\"Rate constant =\",k,\"sec^-1\")\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "Rate constant = 4.61e-04 sec^-1\n"
- ]
- }
- ],
- "prompt_number": 1
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 2 - pg 422"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#calculate the Rate constant\n",
- "#Initialization of variables\n",
- "import math\n",
- "t=10. #min\n",
- "x=90.\n",
- "#calculations\n",
- "k=2.303*math.log10(100/(100-x)) /t\n",
- "#results\n",
- "print '%s %.3f %s' %(\"Rate constant =\",k,\"min^-1\")\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "Rate constant = 0.230 min^-1\n"
- ]
- }
- ],
- "prompt_number": 2
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 3 - pg 427"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#calculate the rate constant\n",
- "#Initialization of variables\n",
- "t=242. #sec\n",
- "P=229. #mm\n",
- "P0=363. #mm\n",
- "#calculations\n",
- "k=(1./P -1./P0)/t\n",
- "#results\n",
- "print '%s %.2e %s' %(\"rate constant=\",k,\"sec^-1 mm^-1\")\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "rate constant= 6.66e-06 sec^-1 mm^-1\n"
- ]
- }
- ],
- "prompt_number": 3
- }
- ],
- "metadata": {}
- }
- ]
-} \ No newline at end of file