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+{
+ "cells": [
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "# Chapter8 Properties of Dilute Solutions"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.2, Pageno.32"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 3,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "molal boiling point constant= 0.513 f deg molalˆ−1\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "R=1.987 #in cal /mole K\n",
+ "T=100.0 #in Celsius\n",
+ "M1=18.02 #in gms\n",
+ "Hvap=539.7 #cal gˆ−1\n",
+ "#CALCULATIONS\n",
+ "Kb=R*(273.1+T)**2*M1/(1000*M1*Hvap)\n",
+ "#RESULTS\n",
+ "Kb=round(Kb,3)\n",
+ "print 'molal boiling point constant=',Kb,'f deg molalˆ−1'"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.3, Pageno.32"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 4,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "molecular weight of dinitrozene = 168.67 g moleˆ−1\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "Kb=2.53 #in deg molalˆ−1\n",
+ "w2=1 #in gms\n",
+ "Tb=0.3 #in Celsius\n",
+ "w1=50 #in gms\n",
+ "#CALCULATIONS\n",
+ "M2=Kb*w2*1000/(Tb*w1)\n",
+ "#RESULTS\n",
+ "M2=round(M2,2)\n",
+ "print 'molecular weight of dinitrozene =',M2,'g moleˆ−1'"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.4, Pageno.33"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 5,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "boiling water of a solution= 0.569 deg\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "mu=5.0 #in gms\n",
+ "Mu=60.06 #in gms\n",
+ "mw=75.0 #in gms\n",
+ "#CALCULATIONS\n",
+ "Tb=0.513*mu*1000/(Mu*mw)\n",
+ "#RESULTS\n",
+ "Tb=round(Tb,3)\n",
+ "print 'boiling water of a solution=',Tb,'deg'"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.5, Pageno.33"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 6,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "Kf of water= 1.859 deg molalˆ−1\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "R=1.987 #in cal moleˆ−1 Kˆ−1\n",
+ "T=0 #in Celsius units\n",
+ "M=18.02 #in gms\n",
+ "Hf=79.7 #in cal gˆ−1\n",
+ "#CALCULATIONS\n",
+ "Kf=R*(273.1+T)**2*M/(1000*M*Hf)\n",
+ "#RESULTS\n",
+ "Kf=round(Kf,3)\n",
+ "print 'Kf of water=',Kf,'deg molalˆ−1'"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.6, Pageno.34"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 7,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "osmotic pressure of sucrose solution= 26.911 atm\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "M=18.02 #in g moleˆ−1\n",
+ "d=0.99564 #in g/ cc\n",
+ "R=0.08205 #in l−atm degˆ−1 moleˆ−1\n",
+ "T=30 #in Celsius\n",
+ "P1=31.824 #in mm\n",
+ "P10=31.207 # in mm\n",
+ "#CALCULATIONS\n",
+ "p=R*(273.15+T)*2.303*1000*d*math.log10(P1/P10)/M\n",
+ "#RESULTS\n",
+ "p=round(p,3)\n",
+ "print 'osmotic pressure of sucrose solution=',p,'atm'"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example 8.7, Pageno.34"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 8,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "osmotic pressure of sucrose solution= 24.86 atm\n"
+ ]
+ }
+ ],
+ "source": [
+ "import math\n",
+ "#initialisation of variables\n",
+ "R=0.082 #in l−atm / mol ˆ−1 Kˆ−1\n",
+ "T=30 #in C\n",
+ "V=1 #in litres\n",
+ "#CALCULATIONS\n",
+ "p=R*(273.15+T)/V \n",
+ "#RESULTS\n",
+ "p=round(p,2)\n",
+ "print 'osmotic pressure of sucrose solution=',p,'atm'"
+ ]
+ }
+ ],
+ "metadata": {
+ "anaconda-cloud": {},
+ "kernelspec": {
+ "display_name": "Python [Root]",
+ "language": "python",
+ "name": "Python [Root]"
+ },
+ "language_info": {
+ "codemirror_mode": {
+ "name": "ipython",
+ "version": 2
+ },
+ "file_extension": ".py",
+ "mimetype": "text/x-python",
+ "name": "python",
+ "nbconvert_exporter": "python",
+ "pygments_lexer": "ipython2",
+ "version": "2.7.11"
+ }
+ },
+ "nbformat": 4,
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+}