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diff --git a/Physical_Chemistry_by_D._Farrington/Chapter8_Properties_of.ipynb b/Physical_Chemistry_by_D._Farrington/Chapter8_Properties_of.ipynb new file mode 100644 index 00000000..12201d3b --- /dev/null +++ b/Physical_Chemistry_by_D._Farrington/Chapter8_Properties_of.ipynb @@ -0,0 +1,249 @@ +{ + "cells": [ + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "# Chapter8 Properties of Dilute Solutions" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.2, Pageno.32" + ] + }, + { + "cell_type": "code", + "execution_count": 3, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "molal boiling point constant= 0.513 f deg molalˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "R=1.987 #in cal /mole K\n", + "T=100.0 #in Celsius\n", + "M1=18.02 #in gms\n", + "Hvap=539.7 #cal gˆ−1\n", + "#CALCULATIONS\n", + "Kb=R*(273.1+T)**2*M1/(1000*M1*Hvap)\n", + "#RESULTS\n", + "Kb=round(Kb,3)\n", + "print 'molal boiling point constant=',Kb,'f deg molalˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.3, Pageno.32" + ] + }, + { + "cell_type": "code", + "execution_count": 4, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "molecular weight of dinitrozene = 168.67 g moleˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "Kb=2.53 #in deg molalˆ−1\n", + "w2=1 #in gms\n", + "Tb=0.3 #in Celsius\n", + "w1=50 #in gms\n", + "#CALCULATIONS\n", + "M2=Kb*w2*1000/(Tb*w1)\n", + "#RESULTS\n", + "M2=round(M2,2)\n", + "print 'molecular weight of dinitrozene =',M2,'g moleˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.4, Pageno.33" + ] + }, + { + "cell_type": "code", + "execution_count": 5, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "boiling water of a solution= 0.569 deg\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "mu=5.0 #in gms\n", + "Mu=60.06 #in gms\n", + "mw=75.0 #in gms\n", + "#CALCULATIONS\n", + "Tb=0.513*mu*1000/(Mu*mw)\n", + "#RESULTS\n", + "Tb=round(Tb,3)\n", + "print 'boiling water of a solution=',Tb,'deg'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.5, Pageno.33" + ] + }, + { + "cell_type": "code", + "execution_count": 6, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "Kf of water= 1.859 deg molalˆ−1\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "R=1.987 #in cal moleˆ−1 Kˆ−1\n", + "T=0 #in Celsius units\n", + "M=18.02 #in gms\n", + "Hf=79.7 #in cal gˆ−1\n", + "#CALCULATIONS\n", + "Kf=R*(273.1+T)**2*M/(1000*M*Hf)\n", + "#RESULTS\n", + "Kf=round(Kf,3)\n", + "print 'Kf of water=',Kf,'deg molalˆ−1'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.6, Pageno.34" + ] + }, + { + "cell_type": "code", + "execution_count": 7, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "osmotic pressure of sucrose solution= 26.911 atm\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "M=18.02 #in g moleˆ−1\n", + "d=0.99564 #in g/ cc\n", + "R=0.08205 #in l−atm degˆ−1 moleˆ−1\n", + "T=30 #in Celsius\n", + "P1=31.824 #in mm\n", + "P10=31.207 # in mm\n", + "#CALCULATIONS\n", + "p=R*(273.15+T)*2.303*1000*d*math.log10(P1/P10)/M\n", + "#RESULTS\n", + "p=round(p,3)\n", + "print 'osmotic pressure of sucrose solution=',p,'atm'" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "## Example 8.7, Pageno.34" + ] + }, + { + "cell_type": "code", + "execution_count": 8, + "metadata": { + "collapsed": false + }, + "outputs": [ + { + "name": "stdout", + "output_type": "stream", + "text": [ + "osmotic pressure of sucrose solution= 24.86 atm\n" + ] + } + ], + "source": [ + "import math\n", + "#initialisation of variables\n", + "R=0.082 #in l−atm / mol ˆ−1 Kˆ−1\n", + "T=30 #in C\n", + "V=1 #in litres\n", + "#CALCULATIONS\n", + "p=R*(273.15+T)/V \n", + "#RESULTS\n", + "p=round(p,2)\n", + "print 'osmotic pressure of sucrose solution=',p,'atm'" + ] + } + ], + "metadata": { + "anaconda-cloud": {}, + "kernelspec": { + "display_name": "Python [Root]", + "language": "python", + "name": "Python [Root]" + }, + "language_info": { + "codemirror_mode": { + "name": "ipython", + "version": 2 + }, + "file_extension": ".py", + "mimetype": "text/x-python", + "name": "python", + "nbconvert_exporter": "python", + "pygments_lexer": "ipython2", + "version": "2.7.11" + } + }, + "nbformat": 4, + "nbformat_minor": 0 +} |