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+{
+ "cells": [
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "# 4: Defects in Crystals"
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {
+ "collapsed": true
+ },
+ "source": [
+ "## Example number 4.1, Page number 97"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 1,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "fraction of vacancy sites at 1000 C is 8.4663 *10**-7\n",
+ "answer varies due to rounding off errors\n"
+ ]
+ }
+ ],
+ "source": [
+ "#importing modules\n",
+ "import math\n",
+ "from __future__ import division\n",
+ "\n",
+ "#Variable declaration \n",
+ "T1=773; #temperature(K)\n",
+ "T2=1273; #temperature(K)\n",
+ "n=1*10**-10; #fraction of vacancy sites\n",
+ "\n",
+ "#Calculations\n",
+ "X=round(T1*math.log(n)/T2,3);\n",
+ "x=math.exp(X); #fraction of vacancy sites at 1000 C\n",
+ "\n",
+ "#Result\n",
+ "print \"fraction of vacancy sites at 1000 C is\",round(x*10**7,4),\"*10**-7\"\n",
+ "print \"answer varies due to rounding off errors\""
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example number 4.2, Page number 98"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 2,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "energy required is 1.971 eV\n"
+ ]
+ }
+ ],
+ "source": [
+ "#importing modules\n",
+ "import math\n",
+ "from __future__ import division\n",
+ "\n",
+ "#Variable declaration \n",
+ "T=273+25; #temperature(K)\n",
+ "m=4; \n",
+ "n=5*10**11; #density(per m**3)\n",
+ "V=(2*2.82*10**-10)**3; #volume(m**3)\n",
+ "kB=8.625*10**-5;\n",
+ "\n",
+ "#Calculations\n",
+ "N=m/V;\n",
+ "Ep=2*kB*T*math.log(N/n);\n",
+ "\n",
+ "#Result\n",
+ "print \"energy required is\",round(Ep,3),\"eV\""
+ ]
+ },
+ {
+ "cell_type": "markdown",
+ "metadata": {},
+ "source": [
+ "## Example number 4.3, Page number 99"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "execution_count": 3,
+ "metadata": {
+ "collapsed": false
+ },
+ "outputs": [
+ {
+ "name": "stdout",
+ "output_type": "stream",
+ "text": [
+ "ratio of frenkel defects is 2.802 *10**-3\n",
+ "answer in the book is wrong\n"
+ ]
+ }
+ ],
+ "source": [
+ "#importing modules\n",
+ "import math\n",
+ "from __future__ import division\n",
+ "\n",
+ "#Variable declaration \n",
+ "T1=273+20; #temperature(K)\n",
+ "T2=273+300; #temperature(K)\n",
+ "Ei=1.4; #energy(eV)\n",
+ "kB=8.625*10**-5;\n",
+ "\n",
+ "#Calculations\n",
+ "x=(1/(2*T1))-(1/(2*T2));\n",
+ "n=1/math.exp((Ei/(2.303*kB))*x); #ratio of frenkel defects\n",
+ "\n",
+ "#Result\n",
+ "print \"ratio of frenkel defects is\",round(n*10**3,3),\"*10**-3\"\n",
+ "print \"answer in the book is wrong\""
+ ]
+ }
+ ],
+ "metadata": {
+ "kernelspec": {
+ "display_name": "Python 2",
+ "language": "python",
+ "name": "python2"
+ },
+ "language_info": {
+ "codemirror_mode": {
+ "name": "ipython",
+ "version": 2
+ },
+ "file_extension": ".py",
+ "mimetype": "text/x-python",
+ "name": "python",
+ "nbconvert_exporter": "python",
+ "pygments_lexer": "ipython2",
+ "version": "2.7.11"
+ }
+ },
+ "nbformat": 4,
+ "nbformat_minor": 0
+}