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diff --git a/Chemical_Reaction_Engineering_by_O._Levenspiel/ch22.ipynb b/Chemical_Reaction_Engineering_by_O._Levenspiel/ch22.ipynb new file mode 100755 index 00000000..ee78ccfc --- /dev/null +++ b/Chemical_Reaction_Engineering_by_O._Levenspiel/ch22.ipynb @@ -0,0 +1,194 @@ +{ + "metadata": { + "name": "" + }, + "nbformat": 3, + "nbformat_minor": 0, + "worksheets": [ + { + "cells": [ + { + "cell_type": "heading", + "level": 1, + "metadata": {}, + "source": [ + "Chapter 22 :\n", + "\n", + "G/L Reactions on Solid \n", + "\n", + "Catalysts: Trickle Beds, Slurry \n", + "\n", + "Reactors, and Three-Phase \n", + "\n", + "Fluidized Beds" + ] + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 22.1 pageno : 511" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "import math \n", + "\n", + "# Variables\n", + "PA = 101325. #Pa\n", + "HA = 36845. #PA.m3.l/mol\n", + "CBo = 1000. #mol/m3\n", + "v = 10**-4 #m3*l/s\n", + "h = 5. #m\n", + "A = 0.1 #m2\n", + "\n", + "# Calculations\n", + "CA = PA/HA;\n", + "FBo = v*CBo;\n", + "Vr = A*h;\n", + "dp = 5*10**-3; #mcat\n", + "d_solid = 4500. #kg/m3cat\n", + "De = 8*10**-10; #m3l/mcat.s\n", + "n = 0.5;\n", + "b = 1.;\n", + "k = 2.35*10**-3;\n", + "L = dp/6.;\n", + "kai_overall = 0.02;\n", + "kac_ac = 0.05;\n", + "f = 0.6;\n", + "#For a half-order reaction\n", + "Mt = L*math.sqrt((n+1)*(k*d_solid*(CA)**(n-1))/(2*De));\n", + "E = 1/Mt;\n", + "rA = (1/((1/(kai_overall))+(1/(kac_ac))+(1/(k*b*(CA**(n-1))*E*f*d_solid))))*(PA/HA);\n", + "#From Material Balance\n", + "XB = b*rA*Vr/FBo;\n", + "\n", + "# Results\n", + "print \" The conversion of acetone is %.3f\"%(XB)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + " The conversion of acetone is 0.158\n" + ] + } + ], + "prompt_number": 2 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 22.2 pageno : 513" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "%matplotlib inline\n", + "\n", + "import math \n", + "from matplotlib.pyplot import *\n", + "from numpy import *\n", + "\n", + "# Variables\n", + "PA = 14.6*101325; #Pa\n", + "HA = 148000.; # liquid\n", + "Vr = 2.;\n", + "Vl = Vr;\n", + "b = 1.;\n", + "fs = 0.0055;\n", + "\n", + "# Calculations\n", + "k = 5.*10**-5; #m6l/kg.molcat.s\n", + "dp = 5*10**-5; #mcat\n", + "kac = 4.4*10**-4;kai = 0.277; #m3l/m3.r.s\n", + "density = 1450.; #kg/m3\n", + "De = 5*10**-10; #m3l/mcat.s\n", + "L = dp/6; #for spherical particle\n", + "CA = PA/HA;\n", + "X = 0.9;\n", + "CBo = 2500.\n", + "CB = CBo*(1-X);\n", + "ac = 6*fs/dp;\n", + "K = kac*ac;\n", + "\n", + "CB = [2500,1000,250];\n", + "e = [0.19,0.29,0.5];\n", + "Mt = zeros(3)\n", + "rA = zeros(3)\n", + "inv_rA = zeros(3)\n", + "for i in range(3):\n", + " Mt[i] = L*math.sqrt(k*CB[i]*density/De);\n", + " rA[i] = CA/((1./kai)+(1./K)+(1./(k*density*e[i]*fs*CB[i])))\n", + " inv_rA[i] = 1/rA[i];\n", + "\n", + "# Results\n", + "plot(CB,inv_rA)\n", + "ylabel(\"1/-rA\")\n", + "Area = 3460.\n", + "t = Vl*Area/(b*Vr);\n", + "t = t/60. #min\n", + "print \" The time required for 90 percentage conversion of reactant is %.f\"%t,\n", + "print \"min\"\n", + "show()\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "Populating the interactive namespace from numpy and matplotlib\n", + " The time required for 90 percentage conversion of reactant is 58" + ] + }, + { + "output_type": "stream", + "stream": "stdout", + "text": [ + " min\n" + ] + }, + { + "output_type": "stream", + "stream": "stderr", + "text": [ + "WARNING: pylab import has clobbered these variables: ['draw_if_interactive', 'e']\n", + "`%pylab --no-import-all` prevents importing * from pylab and numpy\n" + ] + }, + { + "metadata": {}, + "output_type": "display_data", + "png": 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