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+{
+ "metadata": {
+ "name": ""
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter 2: Quantum Mechanics"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.1, Page 79"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "#Variable Declaration\n",
+ "V = 50; # Given potential difference, V\n",
+ "\n",
+ "#Calculations\n",
+ "lamda = 12.24/sqrt(V); # Wavelength of the light, angstrom\n",
+ "\n",
+ "#Result\n",
+ "print \"The de-broglie wavelength of electron = %4.2f angstrom\"%lamda\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The de-broglie wavelength of electron = 1.73 angstrom\n"
+ ]
+ }
+ ],
+ "prompt_number": 1
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.2, Page 79"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "#Variable Declaration\n",
+ "h = 6.62e-34; # Planck's constant, J-s\n",
+ "m0 = 1.6e-27; # Rest mass of proton, kg\n",
+ "c = 3.0e+8; # Speed of light, in m/s\n",
+ "v = c/20; # Velocity of the proton, in m/s\n",
+ "\n",
+ "#Calculations\n",
+ "lamda = (h*sqrt(1-v**2/c**2))/(m0*v);\n",
+ "\n",
+ "#Result\n",
+ "print \"The de broglie wavelength associated with the proton = %4.2e m\"%lamda\n",
+ "#answer differs due to rounding-off errors"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The de broglie wavelength associated with the proton = 2.75e-14 m\n"
+ ]
+ }
+ ],
+ "prompt_number": 14
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.3, Page 79"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "c = 3.0e+8; # Speed of light, m/s\n",
+ "v = 2.0e+8; # Velocity of the proton, m/s\n",
+ "m0 = 1.6e-27; # Rest mass of proton, kg\n",
+ "h = 6.62e-34; # Plancks constant,J-s\n",
+ "\n",
+ "#Calculations\n",
+ "lamda = (h*sqrt(1-(v**2/c**2)))/(m0*v);\n",
+ "\n",
+ "#Result\n",
+ "print \"The wavelength of matter wave associated with the proton = %5.3e m\"%lamda\n",
+ "\n",
+ "#answer differs due to rounding-off errors"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The wavelength of matter wave associated with the proton = 1.542e-15 m\n"
+ ]
+ }
+ ],
+ "prompt_number": 16
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.5, Page 80"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "a = 0.003; # Accuracy of the electron,in percent\n",
+ "s = 5e+03; # Speed of the electron,in m/s\n",
+ "del_v = (a/100)*s; # Change in velocity,in m/s\n",
+ "m0 = 9.1e-31; # Rest mass of the electron,in kg\n",
+ "hcut = 1.054e-34; # Plancks constant,J-s\n",
+ "\n",
+ "#Calculations\n",
+ "del_x = hcut/(2*del_v*m0);\n",
+ "\n",
+ "#Result\n",
+ "print \"The uncertainity in the position of the electron = %4.2e m\"%del_x\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The uncertainity in the position of the electron = 3.86e-04 m\n"
+ ]
+ }
+ ],
+ "prompt_number": 4
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.6, Page 81"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "del_t = 2.5e-14; # Lifetime of the hydrogen atom in excited state\n",
+ "hcut = 1.054e-34; # Planck's constant,in J-s\n",
+ "e = 1.6e-19; # Charge on electron,in C\n",
+ "\n",
+ "#Calculations\n",
+ "del_E = hcut/(2*del_t*e); # Energy of the state, in eV\n",
+ "\n",
+ "#Result\n",
+ "print \"The minimum error in measurement of lifetime of excited state of hydrogen atom = %6.4f eV\"%del_E\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The minimum error in measurement of lifetime of excited state of hydrogen atom = 0.0132 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 5
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.7, Page 81"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "del_x = 1e-09; # Uncertainty in position of the electron, m\n",
+ "m0 = 9.1e-031; # Rest mass of an electron, kg\n",
+ "hcut = 1.054e-034; # Planck's constant,in J-s\n",
+ "\n",
+ "#Calculations\n",
+ "del_v = hcut/(2*del_x*m0); # Uncertainity in velocity of the electron\n",
+ "\n",
+ "#Result\n",
+ "print \"The uncertainity in the velocity of an electron = %4.2e m/s\"%del_v\n",
+ "#Incorrect answer in the textbook"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The uncertainity in the velocity of an electron = 5.79e+04 m/s\n"
+ ]
+ }
+ ],
+ "prompt_number": 6
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.8, Page 81"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "hcut = 1.054e-34; # Reduced Planck's constant, Js\n",
+ "v = 3e+07; # Velocity of the electron, m/s\n",
+ "c = 3e+08; # Speed of light in vacuum, m/s\n",
+ "m0 = 9.1e-31; # Rest mass of an electron, kg\n",
+ "del_v = 3e+08; # Uncertainty in velocity of the electron, m/s\n",
+ "\n",
+ "#Calculations\n",
+ "del_x = (hcut*sqrt(1-v**2/c**2))/(2*m0*del_v);\n",
+ "\n",
+ "#Result\n",
+ "print \"The smallest possible uncertainity in position of the electron = %6.4f angstrom\"%(del_x/1e-010)\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The smallest possible uncertainity in position of the electron = 0.0019 angstrom\n"
+ ]
+ }
+ ],
+ "prompt_number": 7
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.9, Page 82"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "n = 1;\n",
+ "m0 = 9.1e-031; # Mass of the electron, kg\n",
+ "a = 1e-10; # Width of the box, m\n",
+ "h = 6.63e-034; # Planck's constant, J-s\n",
+ "\n",
+ "#Calculations\n",
+ "E = n**2*h**2/(8*m0*a**2);\n",
+ "\n",
+ "#Result\n",
+ "print \"The energy of the electron moving in 1D infinetly high potential box = %5.2e J\"%E\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The energy of the electron moving in 1D infinetly high potential box = 6.04e-18 J\n"
+ ]
+ }
+ ],
+ "prompt_number": 8
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.10, Page 83"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "#n = [1,2]; # Shell numbers for two lowest permitted energy of the electron \n",
+ "m0 = 9.1e-31; # Mass of the electron, kg\n",
+ "a = 2.5e-10; # Width of the box, m\n",
+ "h = 6.63e-34; # Planck's constant, J-s\n",
+ "e = 1.6e-19; # Charge on electron, C\n",
+ "\n",
+ "#Calculations&Results\n",
+ "E = round((h**2)/(8*m0*a**2*e));\n",
+ "for n in range(1,3):\n",
+ " print \"The lowest two permitted energy values of an electron are\"\n",
+ " print E*n**2,\"eV\"\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The lowest two permitted energy values of an electron are\n",
+ "6.0 eV\n",
+ "The lowest two permitted energy values of an electron are\n",
+ "24.0 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 25
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.11, Page 83"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "m0 = 1.67e-27; # Rest mass,in kg\n",
+ "a = 1e-14; # Size of the box\n",
+ "h = 6.63e-34; # Planck's constant,in J-s\n",
+ "n = 1; # Quantum number for lowest energy state\n",
+ "\n",
+ "#Calculations\n",
+ "E_n = n**2*h**2/(8*m0*a**2);\n",
+ "\n",
+ "#Result\n",
+ "print \"The lowest energy of the neutron confined to the nucleus = %4.2e J\"%E_n\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The lowest energy of the neutron confined to the nucleus = 3.29e-13 J\n"
+ ]
+ }
+ ],
+ "prompt_number": 10
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 2.12, Page 83"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "#Variable Declaration\n",
+ "m0 = 9.1e-31; # Rest mass, kg\n",
+ "a = 1e-10; # Length of the box, m\n",
+ "h = 6.62e-34; # Planck's constat, J-s\n",
+ "n1 = 1; # Ground state\n",
+ "n2 = 2; # First excited state\n",
+ "e = 1.6e-19; # Charge on electron, C\n",
+ "\n",
+ "#Calculations\n",
+ "E1 = (n1**2*h**2)/(8*m0*a**2*e);\n",
+ "E2 = (n2**2*h**2)/(8*m0*a**2*e);\n",
+ "del_E = E2-E1; \n",
+ "\n",
+ "#Result\n",
+ "print \"The energy difference between the ground state and the first excited state = %5.1f eV\"%del_E\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "The energy difference between the ground state and the first excited state = 112.9 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 11
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file