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-{
- "metadata": {
- "name": "",
- "signature": "sha256:63ceed8607dc113635851a8fc16e00b5a679fa077f828a47388aa54622bce4ae"
- },
- "nbformat": 3,
- "nbformat_minor": 0,
- "worksheets": [
- {
- "cells": [
- {
- "cell_type": "heading",
- "level": 1,
- "metadata": {},
- "source": [
- "Chapter 18 - Catalysis"
- ]
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 1 - pg 472"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#calculate the Volume \n",
- "#Initialization of variables\n",
- "V1=0.284 #cm^3 /g\n",
- "V2=1.43 #cm^3 /g\n",
- "P1=142.4 #mm\n",
- "P2=760. #mm\n",
- "#calculations\n",
- "z=(1/V1 - 1/V2)/(1/P1 - 1/P2)\n",
- "invVm=1/V2 - z/P2\n",
- "Vm=1/invVm\n",
- "#results\n",
- "print '%s %.1f %s' %(\"Volume =\",Vm,\"cm^3/g\")\n",
- "print 'The answer in the textbook is a bit different due to rounding off error.'\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "Volume = 20.5 cm^3/g\n",
- "The answer in the textbook is a bit different due to rounding off error.\n"
- ]
- }
- ],
- "prompt_number": 1
- },
- {
- "cell_type": "heading",
- "level": 2,
- "metadata": {},
- "source": [
- "Example 2 - pg 477"
- ]
- },
- {
- "cell_type": "code",
- "collapsed": false,
- "input": [
- "#calculate the total area\n",
- "#Initialization of variables\n",
- "Vm=2.86 #cc/g\n",
- "P=1 #atm\n",
- "R=82.06 #cm^3 atm/deg mol\n",
- "T=273.2 #deg\n",
- "N=6.023*10**23\n",
- "sigma=16.2*10**-16 #cm^2 /molecule\n",
- "#calculations\n",
- "n=P*Vm/(R*T)\n",
- "A=N*n*sigma\n",
- "#results\n",
- "print '%s %.2e %s' %(\"total area =\",A,\" cm^2 (g catalyst)^-1\")\n"
- ],
- "language": "python",
- "metadata": {},
- "outputs": [
- {
- "output_type": "stream",
- "stream": "stdout",
- "text": [
- "total area = 1.24e+05 cm^2 (g catalyst)^-1\n"
- ]
- }
- ],
- "prompt_number": 2
- }
- ],
- "metadata": {}
- }
- ]
-} \ No newline at end of file