Removed duplicates

1 files changed, 225 insertions, 0 deletions

diff --git a/Physical_Chemistry_by_D._Farrington/Chapter6_One.ipynb b/Physical_Chemistry_by_D._Farrington/Chapter6_One.ipynb
new file mode 100644
index 00000000..b2dbc759
--- /dev/null
+++ b/Physical_Chemistry_by_D._Farrington/Chapter6_One.ipynb
@@ -0,0 +1,225 @@
+{
+ "cells": [
+  {
+   "cell_type": "markdown",
+   "metadata": {
+    "collapsed": true
+   },
+   "source": [
+    "# Chapter6 One Component Systems"
+   ]
+  },
+  {
+   "cell_type": "markdown",
+   "metadata": {},
+   "source": [
+    "## Example 6.1, Page no.26"
+   ]
+  },
+  {
+   "cell_type": "code",
+   "execution_count": 1,
+   "metadata": {
+    "collapsed": false
+   },
+   "outputs": [
+    {
+     "name": "stdout",
+     "output_type": "stream",
+     "text": [
+      "vapour pressure using ideal gas = 175.647 mm\n",
+      "vapour pressure using equation = 142.673 mm\n"
+     ]
+    }
+   ],
+   "source": [
+    "import math\n",
+    "#initialisation of variables    \n",
+    "G=28.6      #in gms\n",
+    "R=0.08205   #l−atm moleˆ−1 degˆ−1\n",
+    "T=30        #in Celsius\n",
+    "M=153.8     #in gms\n",
+    "v=20.01     #in litres\n",
+    "#CALCULATIONS\n",
+    "p=G*R*(273.1+T)*760/(M*v)\n",
+    "p1=p/(1+(p/760))\n",
+    "#RESULTS\n",
+    "p=round(p,3)\n",
+    "p1=round(p1,3)\n",
+    "print 'vapour pressure using ideal gas =',p,'mm'\n",
+    "print 'vapour pressure using equation =',p1,'mm'"
+   ]
+  },
+  {
+   "cell_type": "markdown",
+   "metadata": {},
+   "source": [
+    "## Example 6.2, Page no.27"
+   ]
+  },
+  {
+   "cell_type": "code",
+   "execution_count": 2,
+   "metadata": {
+    "collapsed": false
+   },
+   "outputs": [
+    {
+     "name": "stdout",
+     "output_type": "stream",
+     "text": [
+      "change in boling point of water per mm = 0.04 deg mmˆ−1\n"
+     ]
+    }
+   ],
+   "source": [
+    "import math\n",
+    "#initialisation of variables  \n",
+    "T=100       #in Celsius\n",
+    "Vv=30.199   #in l moleˆ−1\n",
+    "Vl=0.01878  #in l moleˆ−1\n",
+    "H=539.7     #in cal gˆ−1\n",
+    "m=18.01     #in g moleˆ−1\n",
+    "R=0.04129   #in l−atm cal ˆ−1\n",
+    "#CALCULATIONS\n",
+    "r=H*m*R*760/((273.1+T)*(Vv-Vl))\n",
+    "r1=1/r\n",
+    "#RESULTS\n",
+    "r1=round(r1,2)\n",
+    "print 'change in boling point of water per mm =',r1, 'deg mmˆ−1'"
+   ]
+  },
+  {
+   "cell_type": "markdown",
+   "metadata": {},
+   "source": [
+    "## Example 6.3, Page no.27"
+   ]
+  },
+  {
+   "cell_type": "code",
+   "execution_count": 3,
+   "metadata": {
+    "collapsed": false
+   },
+   "outputs": [
+    {
+     "name": "stdout",
+     "output_type": "stream",
+     "text": [
+      "change in pressure per degree= -132.98 atm deg ˆ−1\n"
+     ]
+    }
+   ],
+   "source": [
+    "import math\n",
+    "#initialisation of variables\n",
+    "T=0      #in Celsius\n",
+    "H=79.7   #in cal gˆ−1\n",
+    "vd=-9.06*10**-5        #in l gˆ−1\n",
+    "R=0.04129              #in l−atm cal ˆ−1\n",
+    "#CALCULATIONS\n",
+    "r=H*R/((273.15+T)*vd)\n",
+    "#RESULTS\n",
+    "r=round(r,2)\n",
+    "print 'change in pressure per degree=',r,'atm deg ˆ−1'"
+   ]
+  },
+  {
+   "cell_type": "markdown",
+   "metadata": {},
+   "source": [
+    "## Example 6.4, Page no.27"
+   ]
+  },
+  {
+   "cell_type": "code",
+   "execution_count": 4,
+   "metadata": {
+    "collapsed": false
+   },
+   "outputs": [
+    {
+     "name": "stdout",
+     "output_type": "stream",
+     "text": [
+      "Heat of vapourization= 10582.14 cal moleˆ−1\n"
+     ]
+    }
+   ],
+   "source": [
+    "import math\n",
+    "#initialisation of variables\n",
+    "y1=32.47*10**-4\n",
+    "y2=34.71*10**-4\n",
+    "x1=1.625\n",
+    "x2=1.107\n",
+    "R=1.987         #in cal moleˆ−1 Kˆ−1\n",
+    "#CALCULATIONS\n",
+    "slope=(x2-x1)/(y2-y1)\n",
+    "Hvap=-slope *2.303*R\n",
+    "#RESULTS\n",
+    "Hvap=round(Hvap,2)\n",
+    "print 'Heat of vapourization=',Hvap,'cal moleˆ−1'"
+   ]
+  },
+  {
+   "cell_type": "markdown",
+   "metadata": {},
+   "source": [
+    "## Example 6.5, Page no.28"
+   ]
+  },
+  {
+   "cell_type": "code",
+   "execution_count": 5,
+   "metadata": {
+    "collapsed": false
+   },
+   "outputs": [
+    {
+     "name": "stdout",
+     "output_type": "stream",
+     "text": [
+      "molar heat of vapourization = 7182 cal mole ˆ−1\n"
+     ]
+    }
+   ],
+   "source": [
+    "import math\n",
+    "#initialisation of variables\n",
+    "H=342      #in cal moleˆ−1 gˆ−1\n",
+    "G=21       #in gms\n",
+    "T=60       #in C\n",
+    "R=1.987    #in cal / mol K\n",
+    "#CALCULATIONS\n",
+    "Hvap=G*H\n",
+    "P1=1/(math.exp(Hvap *9/(2.303*R*(273.1+T)*H)))\n",
+    "#RESULTS\n",
+    "print 'molar heat of vapourization =',Hvap,'cal mole ˆ−1'"
+   ]
+  }
+ ],
+ "metadata": {
+  "anaconda-cloud": {},
+  "kernelspec": {
+   "display_name": "Python [Root]",
+   "language": "python",
+   "name": "Python [Root]"
+  },
+  "language_info": {
+   "codemirror_mode": {
+    "name": "ipython",
+    "version": 2
+   },
+   "file_extension": ".py",
+   "mimetype": "text/x-python",
+   "name": "python",
+   "nbconvert_exporter": "python",
+   "pygments_lexer": "ipython2",
+   "version": "2.7.11"
+  }
+ },
+ "nbformat": 4,
+ "nbformat_minor": 0
+}