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author | kinitrupti | 2017-05-12 18:40:35 +0530 |
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committer | kinitrupti | 2017-05-12 18:40:35 +0530 |
commit | 64d949698432e05f2a372d9edc859c5b9df1f438 (patch) | |
tree | 012fd5b4ac9102cdcf5bc56305e49d6714fa5951 /Introduction_To_Chemical_Engineering_Thermodynamics_by_G._Halder/Ch11.ipynb | |
parent | 9c6ab8cbf3e1a84c780386abf4852d84cdd32d56 (diff) | |
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Revised list of TBCs
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diff --git a/Introduction_To_Chemical_Engineering_Thermodynamics_by_G._Halder/Ch11.ipynb b/Introduction_To_Chemical_Engineering_Thermodynamics_by_G._Halder/Ch11.ipynb deleted file mode 100755 index f82a09fd..00000000 --- a/Introduction_To_Chemical_Engineering_Thermodynamics_by_G._Halder/Ch11.ipynb +++ /dev/null @@ -1,357 +0,0 @@ -{ - "cells": [ - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Chapter 11 - Additional topics in phase equillibrium" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.1 Page: 458" - ] - }, - { - "cell_type": "code", - "execution_count": 4, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.1 - Page: 458\n", - "\n", - "\n", - "Molecular Formula of Sulphur is S8\n" - ] - } - ], - "source": [ - "from __future__ import division\n", - "print \"Example: 11.1 - Page: 458\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "a = 2.423## [g]\n", - "b = 100## [g]\n", - "Lf = 35.7## [cal/g]\n", - "Tf = 353.1## [cal/g]\n", - "delta_Tf = 0.64## [OC]\n", - "R = 2## [cal/mol K]\n", - "Mw = 32## [Molecular wt. of Sulphur, g/mol]\n", - "#*************#\n", - "\n", - "M2 = ((R*Tf**2/(1000*Lf))*(a*1000/(b)))/delta_Tf## [g/mol]\n", - "n = M2/Mw#\n", - "print \"Molecular Formula of Sulphur is S%d\"%(round(n))#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.2 Page: 459" - ] - }, - { - "cell_type": "code", - "execution_count": 5, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.2 - Page: 459\n", - "\n", - "\n", - "Molal Freezing point is 5.10 kg/kmol\n", - "\n" - ] - } - ], - "source": [ - "print \"Example: 11.2 - Page: 459\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "Tf = 5 + 273## [K]\n", - "Lf = 9830## [J/mol]\n", - "R = 8.314## [J/mol K]\n", - "M1 = 78## [kg/kmol]\n", - "#**************#\n", - "\n", - "Kf = R*Tf**2*M1/(1000*Lf)## [kg/kmol]\n", - "print \"Molal Freezing point is %.2f kg/kmol\\n\"%(Kf)#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.3 Page: 458" - ] - }, - { - "cell_type": "code", - "execution_count": 6, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.3 - Page: 458\n", - "\n", - "\n", - "Latent Heat of Fusion of phenol is 26.54 cal/g\n", - "\n" - ] - } - ], - "source": [ - "print \"Example: 11.3 - Page: 458\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "T_melting = 40## [OC]\n", - "Tf = T_melting + 273## [K]\n", - "a = 0.172## [g]\n", - "b = 12.54## [g]\n", - "T_new = 39.25## [OC]\n", - "M2 = 135## [Molecular wt. of acetanilide, g/mol]\n", - "R = 2## [cal/mol K]\n", - "#**************#\n", - "\n", - "delta_T = T_melting - T_new## [OC]\n", - "Kf = delta_T*b*M2/(1000*a)#\n", - "Lv = ((R*Tf**2/(1000)))/Kf## [cal/g]\n", - "print \"Latent Heat of Fusion of phenol is %.2f cal/g\\n\"%(Lv)#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.4 Page: 461" - ] - }, - { - "cell_type": "code", - "execution_count": 7, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.4 - Page: 461\n", - "\n", - "\n", - "Molecular weight of anthracene is 178 kg/kmol\n" - ] - } - ], - "source": [ - "print \"Example: 11.4 - Page: 461\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "T_boiling = 118.24## [OC]\n", - "Tb = T_boiling + 273## [K]\n", - "a = 0.4344## [g]\n", - "b = 44.16## [g]\n", - "Lv = 121## [cal/g]\n", - "T_new = 118.1## [OC]\n", - "R = 2## [cal/mol K]\n", - "#**************#\n", - "\n", - "delta_Tb = T_boiling - T_new## [OC]\n", - "M2 = (R*Tb**2/(1000*Lv))*(a*1000/(b*delta_Tb))#\n", - "print \"Molecular weight of anthracene is %d kg/kmol\"%(round(M2))#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.5 Page: 462" - ] - }, - { - "cell_type": "code", - "execution_count": 1, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.5 - Page: 462\n", - "\n", - "\n", - "Molar Latent Heat of Vaporisation is 31638 J/mol\n" - ] - } - ], - "source": [ - "print \"Example: 11.5 - Page: 462\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "delta_Tb = 2.3## [K]\n", - "w1 = 100## [g]\n", - "M1 = 78## [g/mol]\n", - "w2 = 13.86## [g]\n", - "M2 = 154## [g/mol]\n", - "Tb = 353.1## [K]\n", - "R = 8.314## [J/mol K]\n", - "#****************#\n", - "\n", - "# Molality:\n", - "m = w2*1000/(w1*M2)## [mol/kg]\n", - "# Molal Elevation Constant:\n", - "Kb = delta_Tb/m## [K kg/mol]\n", - "# Molar Latent Heat of Vaporisation:\n", - "Lv = R*Tb**2*M1/(1000*Kb)## [J/mol]\n", - "print \"Molar Latent Heat of Vaporisation is %d J/mol\"%(Lv)#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.6 Page: 465" - ] - }, - { - "cell_type": "code", - "execution_count": 10, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.6 - Page: 465\n", - "\n", - "\n", - "Osmotic Pressure is 594.38 kPa\n", - "\n" - ] - } - ], - "source": [ - "print \"Example: 11.6 - Page: 465\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "Temp = 50 + 273## [K]\n", - "w2 = 60## [g]\n", - "w1 = 1500## [g]\n", - "M1 = 18## [g/mol]\n", - "M2 = 180## [g/mol]\n", - "Vl = 18*10**(-6)## [Molar Volume of water, cubic m/mol]\n", - "R = 8.314## [J/mol K]\n", - "#***************#\n", - "\n", - "# Mole fraction of glucose:\n", - "x2 = (w2/M2)/((w2/M2) + (w1/M1))#\n", - "# Applying Eqn. (11.45):\n", - "P = R*Temp*x2/Vl## [N/square m]\n", - "P = P/1000## [kPa]\n", - "print \"Osmotic Pressure is %.2f kPa\\n\"%(P)#" - ] - }, - { - "cell_type": "markdown", - "metadata": {}, - "source": [ - "## Example: 11.7 Page: 465" - ] - }, - { - "cell_type": "code", - "execution_count": 11, - "metadata": { - "collapsed": false - }, - "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - "Example: 11.7 - Page: 465\n", - "\n", - "\n", - "Osmotic Pressure of the solution is 4.92 atm\n" - ] - } - ], - "source": [ - "print \"Example: 11.7 - Page: 465\\n\\n\"\n", - "\n", - "# Solution\n", - "\n", - "#*****Data******#\n", - "w2 = 0.6## [g]\n", - "w3 = 1.8## [g]\n", - "Temp = 27 + 273## [K]\n", - "V1 = 100## [cubic cm]\n", - "M2 = 60## [g/mol]\n", - "M3 = 180## [g/mol]\n", - "R = 0.082## [L.atm/mol.K]\n", - "#****************#\n", - "\n", - "V1 = V1/1000## [litre]\n", - "# C: Concentration per litre\n", - "C = ((w2/M2) + (w3/M3))/V1## [mol/litre]\n", - "P = C*R*Temp## [atm]\n", - "print \"Osmotic Pressure of the solution is %.2f atm\"%(P)#" - ] - } - ], - "metadata": { - "kernelspec": { - "display_name": "Python 2", - "language": "python", - "name": "python2" - }, - "language_info": { - "codemirror_mode": { - "name": "ipython", - "version": 2 - }, - "file_extension": ".py", - "mimetype": "text/x-python", - "name": "python", - "nbconvert_exporter": "python", - "pygments_lexer": "ipython2", - "version": "2.7.9" - } - }, - "nbformat": 4, - "nbformat_minor": 0 -} |