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author | hardythe1 | 2014-08-06 16:41:00 +0530 |
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committer | hardythe1 | 2014-08-06 16:41:00 +0530 |
commit | d883118364a7a13fa6e139a7dab6fc9a34980a8a (patch) | |
tree | 41afec8408863e1ae835c7adb17e8a4a5b88642d /Heat_And_Thermodynamics/ch6.ipynb | |
parent | 73b0bffc1781c6cf1eec459813767508da507c33 (diff) | |
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1 files changed, 228 insertions, 0 deletions
diff --git a/Heat_And_Thermodynamics/ch6.ipynb b/Heat_And_Thermodynamics/ch6.ipynb new file mode 100755 index 00000000..2a03c0cd --- /dev/null +++ b/Heat_And_Thermodynamics/ch6.ipynb @@ -0,0 +1,228 @@ +{ + "metadata": { + "name": "" + }, + "nbformat": 3, + "nbformat_minor": 0, + "worksheets": [ + { + "cells": [ + { + "cell_type": "heading", + "level": 1, + "metadata": {}, + "source": [ + "Chapter 6 : Change of state" + ] + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 6.1 page no : 194" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "vl = 1; \t\t\t#volume of water in cc\n", + "vs = 1.0908;\t\t\t#volume of ice in cc\n", + "t = 273;\t \t\t#temperature in k\n", + "p = 76*13.6*981;\t\t#pressure in dynes/sq.cm\n", + "l = 80;\t\t\t #latent heat of fusion in cal\n", + "j = 4.2*10**7;\t\t\t#joules consmath.tant in erg/cal\n", + "\n", + "# Calculations\n", + "v = vl-vs;\t\t\t #change in volume\n", + "T = (v*t*p)/(j*l);\t\t\t#change in melting point of water\n", + "\n", + "# Result\n", + "print 'the change in melting point of water is %.5f'%(T)\n", + "print \"there is wrong answer printed in book. Please calculate manually.\"" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "the change in melting point of water is -0.00748\n", + "there is wrong answer printed in book. Please calculate manually.\n" + ] + } + ], + "prompt_number": 2 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 6.2 page no : 195" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "vv = 1674.;\t\t\t#volume of vapour in cc\n", + "vl = 1.;\t\t\t #volume of liquid in cc\n", + "p = 760.;\t\t\t#pressure of steam and water in mm\n", + "t = 373.;\t\t\t#temperature in K\n", + "p1 = 27.12;\t\t\t#superincumbent pressure in mm\n", + "\n", + "# Calculations\n", + "v = vv-vl; \t\t\t#change in volume\n", + "l = (v*p1*t*0.024203/(p));\t\t\t#latent heat of vapourisation in cal\n", + "\n", + "# Result\n", + "print 'the latent heat of vapourisation is %3.1f cal'%(l)\n", + "print \"Note: Answer is slightly different because of rounding error.\"\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "the latent heat of vapourisation is 539.0 cal\n", + "Note: Answer is slightly different because of rounding error.\n" + ] + } + ], + "prompt_number": 6 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 6.3 page no : 195" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "\n", + "# Variables\n", + "m = 1./(342*100);\t\t\t#molar concentration of water\n", + "t = 289.;\t\t\t #temperature in K\n", + "p = 53.5*13.6*981;\t\t\t#pressure in dynes/sq.cm\n", + "\n", + "# Calculations\n", + "k = p/(t*m);\t\t\t #the value of k in ergs/mol.deg\n", + "\n", + "# Result\n", + "print 'the value of k is %.1e ergs/mol.deg'%(k)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "the value of k is 8.4e+07 ergs/mol.deg\n" + ] + } + ], + "prompt_number": 7 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 6.4 pageno : 196" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "p1 = 4.60;\t \t\t #presure at 0deg.C in mm per deg.C\n", + "p2 = 4.94;\t\t \t#pressure at 1deg.C in mm per deg.C\n", + "t = 0.0072;\t\t\t #lowering the melting point in deg.C\n", + "t1 = 7.1563979*10**(-3);\t\t\t#rise in melting point in deg.C\n", + "p = 760;\t\t\t #atmospheric pressure in mm hg\n", + "\n", + "# Calculations\n", + "dp = p2-p1;\t\t\t #rate of increase of pressure in mm per deg.C\n", + "p3 = (t1*p)/t;\t\t\t #pressure in mm\n", + "dt = (755.4-p3)/dp;\t\t\t#tmperature for the triple point in deg.C\n", + "\n", + "# Result\n", + "print 'temperature for the triple point is %3.6f deg.C'%(dt)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "temperature for the triple point is 0.007188 deg.C\n" + ] + } + ], + "prompt_number": 8 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 6.5 pageno : 196" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "# Variables\n", + "v = 21*10**4;\t\t\t#change in volume from vapour to liquid in cc\n", + "Ls = 687;\t\t\t#latent heat of sublimation in cal\n", + "lv = 607;\t\t\t#latent heat of vapourisation in cal\n", + "t = 273;\t\t\t#temperature of water in deg.C\n", + "j = 4.2*10**7;\t\t\t#joules constant in ergs/cal\n", + "\n", + "# Calculations\n", + "sv = lv*j/(t*(v));\t\t\t#slope of vapourisation curve at 0 deg.C in dyne/sq.cm/deg.C\n", + "ss = Ls*j/(t*(v));\t\t\t#slope of sublimation curve at 0 deg.C in dyne/sq.cm/deg.C\n", + "\n", + "# Result\n", + "print 'the slope of vapourisation curve is %.2e dyne/sq.cm/deg.C \\\n", + "\\nthe slope of sublimation curve is %.2e dyne/sq.cm/deg.C'%(sv,ss)\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "the slope of vapourisation curve is 4.45e+02 dyne/sq.cm/deg.C \n", + "the slope of sublimation curve is 5.03e+02 dyne/sq.cm/deg.C\n" + ] + } + ], + "prompt_number": 10 + } + ], + "metadata": {} + } + ] +}
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