clc; warning("off"); printf("\n\n example14.5 - pg730"); // given T=323; //[K] - temperature P=1; //[atm] - pressure Dab_experimental=7.7*10^-6; //[m^2/sec] DPM_A=1.9; // dipole moment of methyl chloride DPM_B=1.6; // dipole moment of sulphur dioxide Vb_A=5.06*10^-2; // liquid molar volume of methyl chloride Vb_B=4.38*10^-2 Tb_A=249; // normal boiling point of methyl chloride Tb_B=263; // normal boiling point of sulphur dioxide del_A=((1.94)*(DPM_A)^2)/(Vb_A*Tb_A); del_B=((1.94)*(DPM_B)^2)/(Vb_B*Tb_B); del_AB=(del_A*del_B)^(1/2); sigma_A=(1.166*10^-9)*(((Vb_A)/(1+1.3*(del_A)^2))^(1/3)); sigma_B=(1.166*10^-9)*(((Vb_B)/(1+1.3*(del_B)^2))^(1/3)); etaabykb=(1.18)*(1+1.3*(del_A^2))*(Tb_A); etabbykb=(1.18)*(1+1.3*(del_B^2))*(Tb_B); sigma_AB=(1/2)*(sigma_A+sigma_B); etaabbykb=(etaabykb*etabbykb)^(1/2); Tstar=T/(etaabbykb); sigmaDnonpolar=1.602; sigmaDpolar=sigmaDnonpolar+(0.19*(del_AB^2))/Tstar; patm=1; Ma=50.488; //[kg/mole] - molecular weight of methyl chloride Mb=64.063; //[kg/mole] - molecular weight of sulphur dioxide D_AB=(1.8583*(10^-(27))*(((T^3)*((1/Ma)+(1/Mb)))^(1/2)))/(patm*(sigma_AB^(2))*sigmaDpolar); printf("\n\n Dab=%em^2/sec",D_AB); printf("\n\n The Chapman Enskog prediction is about 8 percent higher");