clear; clc; funcprot(0); //Example - 2.8 // Page number - 49 printf("Example - 2.8 and Page number - 49\n\n"); //Given T = 0 + 273.15;//[K] - Temperature R = 8.314;//[J/mol*K] - Universal gas constant //Virial equation of state, Z=1+(B/V)+(C/V^(2)) //From above equation we get (Z-1)*V=B+(C/V) P=[50,100,200,400,600,1000]; Z=[0.9846,1.0000,1.0365,1.2557,1.7559,2.0645]; V=zeros(6); k=zeros(6); t=zeros(6); for i=1:6; V(i)=(Z(i)*R*T)/(P(i)*101325);//[m^(3)/mol] k(i)=(Z(i)-1)*V(i); t(i)=1/V(i); end [C,B,sig]=reglin(t',k'); //From the regression, we get intercept=B and slope=C,and thus, printf(" The value of second virial coefficient (B) is %e m^(3)/mol\n",B); printf(" The value of third virial coefficient (C) is %e m^(6)/mol^(2)",C);