clear; clc; // Example: 6.5 // Page: 206 printf("Example: 6.5 - Page: 206\n\n"); // Solution // *****Data******// Tb = -103.9 + 273;// [K] deff('[P] = f1(T)','P = 10^(-(834.13/T) + 1.75*log10(T) - 8.375*10^(-3)*T + 5.324)'); R = 8.314;// [J/mol K] //***************// // From Eqn. 6.60, we get: // d(ln(P))/dT = deltaH/(R*T^2) deff('[P] = f2(T)','P = exp(2.303*log10(f1(T)))'); // Differentiating it with respect to T // d(ln(P))/dT = (834.13*2.303/Tb^2 + 1.75/Tb - 2.303*8.375*10^(-3)) deltaH = R*Tb^2*(834.13*2.303/Tb^2 + 1.75/Tb - 2.303*8.375*10^(-3))/1000;// [kJ/mol] printf("The enthalpy of vaporisation is %.2f kJ/mol\n",deltaH);