clear; //clc(); // Example 6.1 // Page: 108 printf("Example-6.1 Page no.-108\n\n"); //***Data***// T = 20;//[C] m_1 = 0;//[molal] m_2 = 1;//[molal] // The data given in the figure 6.2 , as reported in book, can be repersented with excellent accuracy by a simple data fitting equation //V = 1.0019+0.054668*m-0.000418*m^(2); // Where 'V' is( solution volume, liters per 1000g of water ) and 'm' is the molality of ethanol in water //The partial molal volume is obtained by differentiating the expression of the 'V' with respect to 'm' // v_ethanol = dV/dm = 0.054668-2*0.000418*m // So that at zero molality m = 0;//[molal] // the partial molal volume is v_1 = 0.054668-2*0.000418*m;//[L/mol] // and at m = 1;//[molal] v_2 = 0.054668-2*0.000418*m;//[L/mol] v_1 = v_1*1000;//[cm^(3)/mol] v_2 = v_2*1000;//[cm^(3)/mol] printf("Partial molal volume of ethanol in water at zero molality is %f cm^(3)/mol\n",v_1); printf(" Partial molal volume of ethanol in water at unity molality is %f cm^(3)/mol",v_2);