//Chemical Engineering Thermodynamics //Chapter 4 //Second Law of Thermodynamics //Example 4.4 clear; clc; //Given m1 = 10;//mass of metal block in Kg m2 = 50;//mass of water in Kg Cp1 = 0.09;//Specific heat of metal block in Kcal/Kg K Cp2 = 1;//Specific heat of water in Kcal/Kg K T1 = 50;//Initial temperature of block in deg celsius T2 = 25;//Final temperature of block in deg celsius //To calculate the total change in entropy //Heat lost by block = Heat gained by water Tf = ((m1*Cp1*T1)+(m2*Cp2*T2))/((m1*Cp1)+(m2*Cp2));//final temperature of water in deg celsius Tf1 = Tf+273.16;//final temperature in K del_S1 = m1*Cp1*log(Tf1/(T1+273));//change in entropy of the block in Kcal/K del_S2 = m2*Cp2*log(Tf1/(T2+273));//change in entropy of the block in Kcal/K del_St = del_S1+del_S2; mprintf('The total change entropy is %f Kcal/K',del_St); //end