//Chemical Engineering Thermodynamics //Chapter 4 //Second Law of Thermodynamics //Example 4.1 clear; clc; //Given Q1 = 250;//Heat absorbed in Kcal T1 = (260+273);//Temperature at which engine absorbs heat T0 = (40+273);//Temperature at which engine discards heat //To Calculate work output, heat rejected, entropy change of system,surronding & total change in entropy and the efficiency of the heat engine //(i)Calculation of work output W = (Q1*((T1-T0)/T1));//Work done using equations 4.7 & 4.9 given on page no 98 mprintf('(i)The work output of the heat engine is %f Kcal',W); //(ii)Calculation of heat rejected Q2 = (Q1*T0)/T1; mprintf('\n (ii)The heat rejected is %f Kcal',Q2); //(iii)Calculation of entropy del_S1 = -(Q1/T1);//Change in the entropy of source in Kcal/Kg K del_S2 = Q2/T0;//Change in the entropy of sink in Kcal/Kg K del_St = del_S1+del_S2;//Total change in entropy in Kcal/Kg K mprintf('\n (iii)Total change in entropy is %d confirming that the process is reversible',del_St); //(iv)Calculation of efficiency n = (W/Q1)*100; mprintf('\n (iv)The efficiency of the heat engine is %f percent',n); //end