//Chemical Engineering Thermodynamics //Chapter 14 //Thermodynamics of Chemical Reactions //Example 14.5 clear; clc; //Given T = 298;//Temperature in Kelvin //Standard enthalpy in Kcal/Kgmole of the following components at 298 K are given as H_SO2 = -70960; H_SO3 = -94450; H_O2 = 0; //Standard entropy in Kcal/Kgmole K of the following components at 298 K are given as S_SO2 = 2.48; S_SO3 = -19.7 S_O2 = 0; //Basis: 1 Kgmole of SO2 //SO2 +(1/2)O2 - SO3 //To Calculate the standard free energy for the reaction n_SO2 = 1;//Kgmole of SO2 fed n_O2 = (1/2)*2;//Kgmole of O2 fed as 100% excess O2 is given n_SO3 = n_SO2;//Kgmole of SO3 formed //From equation 14.38 (page no 312) del_F = (H_SO3-(T*S_SO3))-(H_SO2-(T*S_SO2))-(H_O2-(T*S_O2)); mprintf('The standard free energy for the reaction at 25 degree celsius is %f Kcal/Kgmole',del_F); //end