//Chemical Engineering Thermodynamics //Chapter 13 //Thermodynamics in Phase Equilibria //Example 13.6 clear; clc; //Given x1 = 0.1;//Mole fraction of dichloromethane (CCl2H2) x2 = 0.9;//Mole fraction of methyl acetate (C3H6O2) M1 = 85;//Molecular weight of CCl2H2 M2 = 74;//Molecular weight of C3H602 D1 = 1.3163;//Density of CCl2H2 in gm/cc D2 = 0.9279;//Density of C3H6O2 in gm/cc //To Calculate the volume of 10% dichloromethane solution V1 = M1/D1;//Specific volume of pure CCL2H2 in cc/gmole V2 = M2/D2;//Specific volume of C3H6O2 in cc/gmole //From equation 13.62(page no 256)& 13.78 (page no 257) V_e = x1*x2*(1.2672-0.771*x1);//excess volume in cc/gmole V = V1*x1+V2*x2+V_e; mprintf('The volume of 10 percent dichloromethane is %f cc/gmole',V); //end