//Chemical Engineering Thermodynamics //Chapter 13 //Thermodynamics in Phase Equilibria //Example 13.3 clear; clc; //Given x1 = 0.1;//mole fraction of methane x2 = 0.9;//mole fraction of propane P = [28.1 31.6 35.1];//Pressure in Kgf/sq cm are K1 = [5.8 5.10 4.36];//Vapourisation constants of methane at the corresponding presssures K2 = [0.61 0.58 0.56];//Vapourisation constants of propane at the correspondig pressures //To Calculate the bubble point pressure of the solution //From equation 13.27 (page no 245) for i = 1:3 y1(i) = K1(i)*x1;//mole fraction of methane in the vapour phase y2(i)= K2(i)*x2;//mole fraction of propane in the vapour phase y(i) = y1(i)+y2(i);//sum of the mole fraction in the vapour phase end plot(P,y); xtitle("y vs pressure","P","y"); P1 = interpln([y';P],1);// in Kgf/sq cm mprintf('The bubble point pressure of the solution is %f Kgf/sq cm',P1); //end