//Chemical Engineering Thermodynamics //Chapter 13 //Thermodynamics in Phase Equilibria //Example 13.14 clear; clc; //Given P = 760;//Total pressure of the mixture in mmHg T = [80 90 95 100];//Temperature in deg celsius P1 = [87.4 129.0 162.0 187.0];//vapour pressure of 1,1,2,2-tetrachloroethane in mmHg P2 = [356 526 648 760];//Vapour pressure of water in mmHg //To Calculate the composition of the vapour evolved clf; plot2d(T,P1,style=3); plot2d(T,P2,style=5); xtitle(" ","Temp in deg cel","Vapour pressure in mmHg"); legend("1,1,2,2-tetrachloroethane","Water"); //From the graph we conclude that at 93.8 deg cel P1 = 155;//in mm Hg P2 = 605;//in mm Hg y_1 = P1/P; y_2 = P2/P; mprintf('Mole fraction of 1,1,2,2-tetrachloroethane in vapour is %f',y_1); mprintf('\n Mole fraction of water in vapour is %f',y_2); //end